Thermal properties and curing kinetics of epoxy powder coatings containing graphene nanoplatelets

Andrielen Braz Vanzetto; Lucas Dall Agnol; Alessandra Lavoratti; Marcos Vinícius Marocco; Gabriel Gonem de Lima; Lilian Vanessa Rossa Beltrami; Ademir José Zattera; Diego Piazza

Korean Journal of Chemical Engineering, Vol.38, No.9, 1946-1955, September, 2021

DOI10.1007/s11814-021-0848-7 Export Citation

Thermal properties and curing kinetics of epoxy powder coatings containing graphene nanoplatelets

Andrielen Braz Vanzetto^†, Lucas Dall Agnol¹, Alessandra Lavoratti, Marcos Vinícius Marocco², Gabriel Gonem de Lima², Lilian Vanessa Rossa Beltrami, Ademir José Zattera, and Diego Piazza

Postgraduate Program in Process and Technology Engineering (PGEPROTEC), University of Caxias do Sul (UCS), Caxias do Sul, RS - Brazil
¹Postgraduate Program in Materials Science and Engineering (PGMAT), University of Caxias do Sul (UCS), Caxias do Sul, RS - Brazil
²Laboratory of Polymers (LPOL), University of Caxias do Sul (UCS), 1190 Francisco Getúlio Vargas St. Caxias do Sul, RS - Brazil

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Graphene nanoplatelets (GNP) have excellent properties, such as high mechanical strength and good thermal conductivity, making them interesting nanofiller for their application in powder coatings. In this context, the aim of this study was to evaluate the thermal behavior and the curing kinetics of epoxy powder coatings containing GNP. The coatings were obtained by mixing in a ball mill followed by homogenization in molten state. The GNP were dispersed directly into the epoxy powder. The morphology, thermal stability and curing kinetics of the samples were evaluated. During the curing process, the GNP accelerated the onset of the reaction but ultimately caused steric impediment. From the results, the GNP incorporated to the solid epoxy resin for coatings behaved differently in each stage of the curing process. In general, while the direct dispersion of GNP in powder epoxy by dry mixing methods was not ideal, the thermal properties were improved, with GNP inducing a poor curing state where diffusion phenomena are predominant.

Keywords:Epoxy Powder Coatings;Graphene Nanoplatelets;Curing Kinetics;Thermal Properties

[References]

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[1] Zaman I, Phan TT, Kuan HC, Meng QS, La LTB, Luong L, Youssf O, Ma J, Polymer, 52(7), 1603 (2011)

[2] International Organization for Standardization. ISO 80004-13: Graphene and related two-dimensional (2D) materials (2017).

[3] Park JK, Kim DS, Polym. Eng. Sci., 54, 969 (2014)

[4] Li B, Zhong WH, J. Mater. Sci., 46(17), 5595 (2011)

[5] Liu D, Zhao W, Liu S, Cen Q, Xue Q, Surf. Coat. Technol., 286, 354 (2016)

[6] Kuila T, Bose S, Mishra AK, Khanra P, Kim NH, Lee JH, Prog. Mater. Sci., 57(7), 1061 (2012)

[7] Nonahal M, Rastin H, Saeb MR, Sari MG, Moghadam MG, Zarrintaj P, Ramezanzadeh B, Prog. Org. Coat., 14, 233 (2018)

[8] Tang LC, Wan YJ, Yan D, Pei YB, Zhao L, Li YB, Wu LB, Jiang JX, Lai GQ, Carbon, 60, 16 (2013)

[9] Das TK, Prusty S, Polym-Plast. Technol., 52, 319 (2013)

[10] Gorrasi G, Sarno M, Di Bartolomeo A, Sannino D, Ciambelli P, Vittoria V, J. Polym. Sci. B: Polym. Phys., 45(5), 597 (2007)

[11] Jouyandeh M, Paran SMR, Jannesari A, Saeb MR, Prog. Org. Coat., 127, 429 (2019)

[12] Ferdosian F, Ebrahimi M, Jannesari A, Thermochim. Acta, 568, 67 (2013)

[13] Hardis R, Jessop JLP, Peters FE, Kessler MR, Compos. Part A Appl. Sci. Manuf., 49, 100 (2013)

[14] Vyazovkin S, Chrissafis K, Di Lorenzo ML, Koga N, Pijolat M, Roduit B, Sbirrazzuoli N, Sunol JJ, Thermochim. Acta, 590, 1 (2014)

[15] Jouyandeh M, Yarahmadi E, Didehban K, Ghiyasi S, et al., Prog. Org. Coat., 136, 105217 (2019)

[16] Wang Y, Yu J, Dai W, Song Y, Wang D, Zeng L, Jiang N, Polym. Compos., 36, 556 (2015)

[17] Wang Y, Shan JW, Weng GJ, J. Appl. Phys., 118, 065101 (2015)

[18] Wang F, Drzal LT, Qin Y, Huang Z, High Perform. Polym., 28, 525 (2016)

[19] Vyazovkin S, Burnham AK, Criado JM, Perez-Maqueda LA, Popescu C, Sbirrazzuoli N, Thermochim. Acta, 520(1-2), 1 (2011)

[20] Agnol LD, Dias FTG, Nicoletti NF, Marinowi D, et al.,, Biomater. Appl., 34(5), 673 (2019)

[21] Opfermann J, J. Therm. Anal. Calorim., 60(2), 641 (2000)

[22] Kopsidas S, Olowojoba GB, Kinloch AJ, Taylor AC, Int. J. Adhes. Adhes., 104, 102723 (2021)

[23] El Achaby M, Arrakhiz FZ, Vaudreuil S, Essassi EM, Qaiss A, Bousmina M, J. Appl. Polym. Sci., 127(6), 4697 (2013)

[24] Zhi M, Huang W, J. Wuhan Univ. Technol., 31, 1155 (2016)

[25] Mafi R, Mirabedini SM, Naderi R, Attar MM, Corrosion Sci., 50, 3280 (2008)

[26] Szeluga U, Pusz S, Kumanek B, Olszowska K, Kobyliukh A, Trzebicka B, Crit. Rev. Solid State Mater. Sci., 46, 152 (2020)

[27] Acocella MR, Corcione CE, Giuri A, Maggio M, Maffezzoli A, Guerra G, RSC Adv., 6(28), 23858 (2016)

[28] Lavoratti A, Zattera AJ, Amico SC, J. Appl. Polym. Sci., 135, 46724 (2018)

[29] Romanzini D, Frache A, Zattera AJ, Amico SCJ, J. Phys. Chem. Solids, 87, 9 (2015)

[30] Surnova A, Balkaev D, Musin D, Amirov R, Dimiev AM, Composites, Part B, 162, 685 (2019)

[31] Prolongo MG, Salom C, Arribas C, Sanchez-Cabezudo M, Masegosa RM, Prolongo SG, J. Therm. Anal. Calorim., 125(2), 629 (2016)

[32] Nonahal M, Saeb MR, Jafari SH, Rastin H, Khonakdar HA, Najafi F, Simon F, Polym. Compos., 39, E2016 (2018)

[33] Ferrari VC, Azevedo MF, David LH, Lourenco VL, Polimeros, 24(1), 123 (2014)

[34] Erceg M, Kresic I, Vrandecic NS, Jakic M, J. Therm. Anal. Calorim., 131(1), 325 (2018)

[35] Naderi M, Hoseinabadi M, Najafi M, Motahari S, Shokri M, J. Appl. Polym. Sci., 135, 46201 (2018)