화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.102, 251-259, October, 2021
DOI10.1016/j.jiec.2021.07.008  Export Citation
Preparation of highly dispersed Cu catalysts from hydrotalcite precursor for the dehydrogenation of 1,4-butanediol
Haolan Liu1, Yuanyuan Jiang1, Huaiyuan Zhao1, and Zhaoyin Hou1, 2, †
  • 1Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemistry, Zhejiang University, Hangzhou 310028, China
  • 2Center of Chemistry for Frontier Technologies, Department of Chemistry, Zhejiang University, Hangzhou 310028, China
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Copper-based catalysts are widely used in methanol synthesis, selective catalytic reduction of NOx, hydrogenation, dehydrogenation and hydrogenolysis reactions. In this work, a series of Cux/ Zn3-0.5xMg3-0.5xAl2O9-x catalysts were prepared via the controlled calcination and reduction of hydrotalcite-like structured CuxZn3-0.5xMg3-0.5xAl2(OH)16CO3 precursors. The formation process of Cu2/ Zn2Mg2Al2O7 from Cu2Zn2Mg2Al2(OH)16CO3 was characterized via several techniques. Characterizations results indicated that the dispersion of Cu in reduced Cu2/Zn2Mg2Al2O7 reached 79.3%, and it exhibited excellent activity for the dehydrogenation of 1,4-butanediol (1,4-BDO) to γ-butyrolactone (GBL). The detected conversion of 1,4-BDO reached 99.2% with a 99.5% selectivity of GBL at 240 °C, 0.1 MPa and LHSV-1 = 0.13 h, and the calculated productivity of GBL was 7.07 g-GBL/g-cat/h. And Cu2/Zn2Mg2Al2O7 could maintain its activity within 50 h on stream.
Keywords:Hydrotalcite;1,4-Butanediol;Dehydrogenation;γ-Butyrolactone
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