Cobalt substituted layered O3 and P2-type Na-Ti-Ni-Co-O anode materials for emerging sodium-ion batteries

K. Kannan; M. Kouthaman; P. Arjunan; R. Subadevi; M. Sivakumar

Journal of Industrial and Engineering Chemistry, Vol.102, 363-369, October, 2021

DOI10.1016/j.jiec.2021.07.021 Export Citation

Cobalt substituted layered O3 and P2-type Na-Ti-Ni-Co-O anode materials for emerging sodium-ion batteries

K. Kannan, M. Kouthaman, P. Arjunan, R. Subadevi^†, and M. Sivakumar^†

#120, Energy Materials Lab, Department of Physics, Alagappa University, Karaikudi-630 003, Tamil Nadu, India

E-mail:,

Sodium ion batteries (SIBs) are considered as a propitious candidate for large scale energy storage devices due to the copious of sodium resources in earth crust and low cost. In this work, layered Cobalt (Co) substituted O3-type NaTi0.6Ni0.3Co0.1O2 (O3-NTNC) and P2-type Na0.5Ti0.6Ni0.3Co0.1O2 (P2-NTNC) anode materials were prepared by solid-state reaction for SIBs. The prepared O3-NTNC and P2-NTNC can be assigned to rhombohedral and hexagonal structure with the space group of R-3m and P63/mmc respectively, using Rietveld refinement. O3-NTNC and P2-NTNC delivered the reversible capacity of 108 and 96 mAh g-1 at 0.1C and revealed coulombic efficiency over 90% even after 50 cycles. In addition, partial Co-substitution enhanced the structural stability of the obtained materials during sodiation and desodiation process.

Keywords:O3 and P2-type;Anode materials;Co-substitution;Sodium-ion batteries

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[2] Kouthaman M, Arjunan P, Kannan K, Subadevi R, Kumaran V, Sivakumar M, Mater. Lett., 285, 129119 (2020)

[3] Li XF, Zhou SB, Wu Q, Wang XJ, Yao T, Zhang YM, Song B, Solid State Ion., 334, 14 (2019)

[4] Kouthaman M, Arjunan P, Kannan K, Priyanka V, Subadevi R, Kumaran V, Gnanamuthu RM, Sivakumar M, J. Taiwan Inst. Chem. Eng., 1 (2020).

[5] YTF, Sari HMK, Li X, Wang F, Zhu YR, Hu J, Zhang J, Li X, Nano Energy, 85 (2021)

[6] Yi TF, Pan JJ, Wei TT, Li Y, Cao G, Nano Today, 33, 100894 (2020)

[7] Yu H, Ren Y, Xiao D, Guo S, Zhu Y, Qian Y, Gu L, Zhou H, Angew. Chem.-Int. Edit., 53(34), 8963 (2014)

[8] Hou J, Song J, Niu Y, Cheng C, He H, Li Y, Xu M, J. Solid State Electrochem., 19(6), 1827 (2015)

[9] Zhao C, Avdeev M, Chen L, Hu YS, Angew. Chem.-Int. Edit., 57(24), 7056 (2018)

[10] Wang PF, Yao HR, Zuo TT, Yin YX, Guo YG, Chem. Commun, 53(12), 1957 (2017)

[11] Kannan K, Kouthaman M, Arjunan P, Subadevi R, Sivakumar M, Mater. Lett., 127950 (2020).

[12] Kannan K, Kouthaman M, Arjunan P, Priyanka V, Subadevi R, Kumaresan L, Sivakumar M, Inorg. Chem. Commun., 124, 108383 (2020)

[13] Fielden R, Obrovac MN, J. Electrochem. Soc., 161(6), A1158 (2014)

[14] Wang Y, Yu X, Xu S, Bai J, Xiao R, Hu YS, Li H, Yang XQ, Chen L, Huang X, Nat. Commun., 4(1), 1 (2013)

[15] Guo S, Yu H, Liu P, Ren Y, Zhang T, Chen M, Ishida M, Zhou H, Energy Environ. Sci., 8(4), 1237 (2015)

[16] Wang J, Qiu B, He X, Tisthaus T, Liu H, Stan MC, Schulze S, Xia Y, Liu Z, Winter M, Li J, Chem. Mater., 27(12), 4374 (2015)

[17] Cao Y, Zhang Q, Wei Y, Guo Y, Zhang Z, Huang W, Yang K, Chen W, Zhai T, Li H, Cui Y, Adv. Funct. Mater., 30(7), 190702 (2020)

[18] Shanmugam R, Lai W, ECS Electrochem. Lett., 3(4), A23 (2014)

[19] Mathiyalagan K, Ponnaiah A, Karuppiah K, Rengapillai S, Marimuthu S, Ionics, 26(8), 3929 (2020)

[20] Kouthaman M, Kannan K, Arjunan P, Meenatchi T, Subadevi R, Sivakumar M, Mater. Lett., 276, 128181 (2020)

[21] Rajkumar P, Diwakar K, Subadevi R, Gnanamuthu RM, Sivakumar M, Curr. Appl. Phys., 19, 902 (2019)

[22] Krishnaveni K, Subadevi R, Sivakumar M, Raja M, Kumar TP, J. Sulfur Chem., 40(4), 377 (2019)

[23] Yi TF, Qiu LY, Mei J, Qi SY, Cui P, Luo S, Zhu YR, Xie Y, He YB, Sci. Bull., 65(7), 546 (2020)

[24] Yi TF, Qu JP, Lai X, Han X, Chang H, Zhu YR, Mater. Today Chem., 19, 100407 (2021)

[25] Yi TF, Chang H, Wei TT, Qi SY, Li Y, Zhu YR, J. Mater., 7(3), 563 (2021)

[26] Kuang M, Li TT, Chen H, Zhaeng SM, Zhang LL, Zhang YX, Nanotechnology, 26, 304002 (2015)

[27] Guo S, Liu P, Sun Y, Zhu K, Yi J, Chen M, Ishida M, Zhou H, Angew. Chem., 127 (2015), 11867 (1871).

[28] Zhang Y, Pei Y, Liu W, Zhang S, Xie J, Xia J, Nie S, Liu L, Wang X, Chem. Eng. J., 382, 122697 (2020)

[29] Zhang Z, Yu M, Yang B, Jin C, Guo G, Qiu J, Mater. Res. Bull., 126, 110855 (2020)