Effect of plasma atmosphere on the oxygen transport of mixed ionic and electronic conducting hollow fiber membranes

F. Buck; K. Wiegers; A. Schulz; T. Schiestel

Journal of Industrial and Engineering Chemistry, Vol.104, 1-7, December, 2021

DOI10.1016/j.jiec.2021.08.044 Export Citation

Effect of plasma atmosphere on the oxygen transport of mixed ionic and electronic conducting hollow fiber membranes

F. Buck^{1, 2}, K. Wiegers³, A. Schulz³, and T. Schiestel^{1, †}

¹Fraunhofer Institute for Interfacial Engineering and Biotechnology IGB, 70569 Stuttgart, Germany
²Institute of Physical Chemistry and Electrochemistry, Leibniz Universitat Hannover, 30167 Hannover, Germany
³Institute of Interfacial Process Engineering and Plasma Technology, Universitat Stuttgart, 70569 Stuttgart, Germany

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Perovskite hollow fibers have been used to extract oxygen from different oxygen containing plasmas. The influence of the working length and the temperature on the oxygen transport of (La0.6Ca0.4)(Co0.8Fe0.2)O3-δ(LCCF) hollow fiber membranes in an air and a CO2 plasma were investigated and compared with a conventional electrically heated oven system at a similar temperature. High-quality LCCF hollow fiber membranes were prepared via phase inversion spinning and sintering. In the CO2 plasma, the feasibility of the oxygen extraction due to the CO2 splitting according to CO2 ⇄ CO + ½ O2 was studied. For an active membrane length of 0.5 cm, oxygen permeation values of 17.27 ml min-1 cm-2 in an air plasma at 0.67 kW and 4.97 ml min-1 cm-2 in a CO2 plasma at 1 kW were reached.

Keywords:Plasma;Ceramic hollow fiber membrane;CO2 conversion;Oxygen permeation;Mixed ionic electronic conductor

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[1] Dyatlov S, Didenko N, Ivanova E, Soshneva E, Kulik S, I.O.P. Conf Ser.: Earth Environ. Sci., 434 (2020).

[2] IEA, CO2 emissions from fuel combustion.

[3] Kwak HS, Uhm HS, Hong YC, Choi EH, Sci. Rep., 5, 1 (2015)

[4] Schenk PM, Thomas-Hall SR, Stephens E, Marx UC, Mussgnug JH, Posten C, Kruse O, Hankamer B, Bioenergy research, 1, 20 (2008)

[5] Albo J, Alvarez-Guerra M, Castano P, Irabien A, Green Chem., 17, 2304 (2015)

[6] Liang W, Cao Z, He G, Caro J, Jiang H, ACS Sustainable Chemistry & Engineering, 5, 8657 (2017).

[7] Marin CM, Popczun EJ, Nguyen-Phan TD, Alfonso D, Waluyo I, Hunt A, Kauffman DR, Appl. Catal. B: Environ., 284 (2021)

[8] Bogaerts A, Berthelot A, Heijkers S, Kolev S, Snoeckx R, Sun S, Trenchev G, Van Laer K, Wang W, Plasma Sour. Sci. Technol., 26 (2017)

[9] Ashford B, Tu X, Curr. Opin. Green Sustain. Chem., 3, 45 (2017)

[10] Bogaerts A, Neyts EC, ACS Energy Lett., 3, 1013 (2018)

[11] Weltmann KD, Kolb JF, Holub M, Uhrlandt D, Simek M, Ostrikov K, Hamaguchi S, Cvelbar U, Cernak M, Locke B, Plasma Process. Polym., 16, 180011 (2019)

[12] Bogaerts A, Kozak T, Van Laer K, Snoeckx R, Faraday Discuss., 183, 217 (2015)

[13] Fridman A, Plasma chemistry, Cambridge University Press, 2008.

[14] Snoeckx R, Bogaerts A, Chem. Soc. Rev., 46, 5805 (2017)

[15] Leins M, Baumgartner KM, Walker M, Schulz A, Schumacher U, Stroth U, Plasma Process. Polym., 4, S493 (2007)

[16] Tendero C, Tixier C, Tristant P, Desmaison J, Leprince P, Spectroc. Acta Pt. B-Atom. Spectr., 61, 2 (2006)

[17] Rusanov V, Fridman A, Sholin G, Soviet Phys. Uspekhi, 24, 447 (1981)

[18] Chen G, Buck F, Kistner I, Widenmeyer M, Schiestel T, Schulz A, Walker M, Weidenkaff A, Chem. Eng. J. (2019).

[19] Teraoka Y, Nobunaga T, Yamazoe N, Chem. Lett., 17, 503 (1988)

[20] Burggraaf AJ, Cot L, Fundamentals of inorganic membrane science and technology, fourth ed., Elsevier, 1996.

[21] Stevenson JW, Armstrong TR, Carneim RD, Pederson LR, Weber WJ, J. Electrochem. Soc., 143(9), 2722 (1996)

[22] Schiestel T, Kilgus M, Peter S, Caspary KJ, Wang H, Caro J, J. Membr. Sci., 258(1-2), 1 (2005)

[23] Feldhoff A, Martynczuk J, Arnold M, et al., J. Solid State Chem., 182, 2961 (2009)

[24] Li CD, Chew JJ, Mahmoud A, Liu SM, Sunarso J, J. Membr. Sci., 567, 228 (2018)

[25] Buck F, Feldhoff A, Caro J, Schiestel T, Sep. Purif. Technol., 259 (2021)

[26] Czuprat O, Arnold M, Schirrmeister S, Schiestel T, Caro J, J. Membr. Sci., 364(1-2), 132 (2010)

[27] Efimov K, Klande T, Juditzki N, Feldhoff A, J. Membr. Sci., 389, 205 (2012)

[28] Salehi M, Sogaard M, Esposito V, Foghmoes SPV, Persoon ES, Schroeder M, Hendriksen PV, J. Membr. Sci., 542, 245 (2017)

[29] Buck F, Kistner I, Rosler C, Schulz A, Walker M, Tovar G, Schiestel T, Chem. Ingenieur Tech., 91, 1117 (2019)

[30] Chen G, Liu W, Widenmeyer M, Ying P, Dou M, Xie W, Bubeck C, Wang L, Fyta M, Feldhoff A, J. Membr. Sci., 590 (2019)