화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.104, 61-72, December, 2021
DOI10.1016/j.jiec.2021.08.010  Export Citation
Metal-organic framework based on Co and 4,40-dimethylenebiphenyl diphosphonic acid as an efficient methylene blue adsorbent
Alemayehu Kidanemariam, and Juhyun Park†
  • Department of Intelligent Energy and Industry, School of Chemical Engineering and Materials Science, Institute of Energy-Converting Soft Materials, Chung-Ang University, Seoul 06974, Korea
E-mail:
Dyestuff in industrial wastewater continues to entail environmental pollution and thus developing an adsorbent with superior adsorption performance is urgently required for the survival of future generations. In this work, a novel Co. and H4dbp based metal-organic framework (MOF, denoted as Co-MOF) adsorbent was developed for the removal of methylene blue (MB) from aqueous solution. Hydrothermal synthesis was employed for the fabrication of the Co-MOF with phosphonic acid organic ligand. X-ray diffraction, Fourier-transform infrared spectroscopy, field emission-scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and N2 adsorption-desorption isothermal analysis were utilized for Co-MOF characterization. MB adsorption by as-prepared adsorbent obeys pseudo-second-order adsorption kinetics and follows Langmuir isotherm model with the maximum adsorption capacity of 147.99 mg g-1, which is superior to other analogies. Furthermore, the recoverability of this adsorbent material was astonishing with an excellent MB removal capacity of 89.34 % of initial dye concentration after the fifth cycle. The thermodynamic parameters affirm that this adsorption process exhibits a spontaneous endothermic process with sufficient molecular randomness due to the adsorbent-adsorbate interaction suggesting a great potentiality as an adsorbent to be used for industrial wastewater treatment to mitigate the environment.
Keywords:Dye adsorption;MOF adsorbent;MB adsorption;Aqueous solutions;Industrial wastewater treatment;Co-MOF
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