화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.104, 362-380, December, 2021
DOI10.1016/j.jiec.2021.08.033  Export Citation
A review on the properties and applications of chitosan, cellulose and deep eutectic solvent in green chemistry
Xin Xiong Chang, Nabisab Mujawar Mubarak†, Shaukat Ali Mazari1, Abdul Sattar Jatoi1, Awais Ahmad2, Mohammad Khalid3, Rashmi Walvekar4, E.C. Abdullah5, Rama Rao Karri6, M.T.H Siddiqui7, and Sabzoi Nizamuddin7
  • Department of Chemical and Energy Engineering, Faculty of Engineering and Science, Curtin University, 98009 Miri Sarawak, Malaysia
  • 1Department of Chemical Engineering, Dawood University of Engineering and Technology, Karachi 74800, Pakistan
  • 2Departamento de Quimica Organica, Universidad de Cordoba, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, E14014 Cordoba, Spain
  • 3Graphene & Advanced 2D Materials Research Group (GAMRG), School of Engineering and Technology, Sunway University, No. 5, Jalan Universiti, Bandar Sunway, 47500 Petaling Jaya, Selangor, Malaysia
  • 4Department of Chemical Engineering, School of New Energy and Chemical Engineering, Xiamen University Malaysia, Jalan Sunsuria, Bandar Sunsuria, Sepang 43900, Selangor, Malaysia
  • 5Department of Chemical Process Engineering, Malaysia-Japan International Institute of Technology (MJIIT), Universiti Teknologi Malaysia (UTM), Jalan Sultan Yahya Petra, 54100 Kuala Lumpur, Malaysia
  • 6Petroleum, and Chemical Engineering, Faculty of Engineering, Universiti Teknologi Brunei, Brunei Darussalam
  • 7School of Engineering, RMIT University, Melbourne 3000, Australia
E-mail:
The concept of green chemistry has attracted attention due to the green synthesis and ecofriendly nature of the compounds leading to the green and sustainable chemical industries and processes. Chitosan is anecofriendly material, which is biodegradable, non-toxic, and biocompatible. It has the potential to be modified into biofilms for various applications such as biomedical, packaging, and pharmaceutical fields. Nevertheless, some poor properties of chitosan restrict its wide applications. The incorporation of nanocellulose fillers into chitosan matrix can enhance the mechanical and thermal properties of chitosan. Cellulose nanomaterials can be achieved through chemical and mechanical modifications. The common type of nanocellulose are cellulose nanofibers (CNFs), cellulose nano-whiskers (CNWs), tunicate CNCs (t-CNCs), algae cellulose particles (AC) and bacterial cellulose particles (BC). Nanocellulose are applied as the reinforcement fillers in various polymer matrices such as polysaccharides, proteins, lipids, polylactic acid etc. Deep eutectic solvents (DES) are relatively novel green solvents, which can be applied in various fields. DES are widely applied in metal processing, polymer processing and synthesis. Even though there are not much studies available on DES for synthesis of nanocomposite films; however they are used as eco-friendly solvents in manufacturing processes. This study reviews the discovery, structure, properties of chitosan and cellulose, their derivatives and applications. In addition, the paper also discusses the properties of DES and their applications.
Keywords:Deep eutectic solvent;Chitosan;Cellulose nanofibers;Cellulose nano-whiskers;Algae cellulose particles;Bacterial cellulose particles
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