Efficient degradation of azo dye by dual-doped photo-enhanced Fentonlike catalysts in magnetic suspension reactor

Ting Dai; Chang Li; Ning Wang; Li Yu; Meng Zhang

Journal of Industrial and Engineering Chemistry, Vol.104, 390-396, December, 2021

DOI10.1016/j.jiec.2021.08.031 Export Citation

Efficient degradation of azo dye by dual-doped photo-enhanced Fentonlike catalysts in magnetic suspension reactor

Ting Dai, Chang Li, Ning Wang^†, Li Yu^{1, †}, and Meng Zhang²

National Engineering Laboratory for Fiber Optic Sensing Technology, Wuhan University of Technology, Wuhan 430070, China
¹Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, School of Materials Science , Hubei University, Wuhan 430062, China
²Institute of Environment and Health, Hubei Key Laboratory Of Persistent Toxic Pollutants Environment And Health Effects, Jianghan University, Wuhan 430056, China

E-mail:,

Fenton-like catalysts have sparked enormous interest from academic to industrial fields because of their excellent degradability and offered a promising platform for the effective treatment of wastewater. However, it remains a grand challenge to balance their catalytic performance and corrosion resistance for industrial application. To address this issue, we report Cr and C dual-doped photo-enhanced Fenton-like catalysts (Cr, C-FeSiB) in which Cr functions as a corrosion inhibitor to improve recycling performance and C acts as an electron transfer accelerator to raise the cycle efficiency of iron ions during complex Fenton-like reactions. Moreover, we design a low energy-consumption magnetic-suspensionlike reactor in which Fenton-like catalysts can work as micro-scaled stirrers to enhance the mass transfer efficiency during the Fenton-like reactions owing to their soft magnetic property.

Keywords:Fe-based amorphous catalyst;Dual-doped;Magnetic suspension reactor;Photo-Fenton

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[23] Bezerra CWB, Zhang L, Lee K, Liu H, Marques ALB, Marques EP, Wang H, Zhang J, Electrochim. Acta (2008).

[24] Madhuvilakku R, Piraman S, Bioresour. Technol. (2013).

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[27] Chu SC, Shen B, Wang Q, Chen M, Lin P, Cui, Z (2018).

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