Pt supported on hierarchical porous carbon for furfural hydrogenation

Mi Yeon Byun; Man Sig Lee

Journal of Industrial and Engineering Chemistry, Vol.104, 406-415, December, 2021

DOI10.1016/j.jiec.2021.08.038 Export Citation

Pt supported on hierarchical porous carbon for furfural hydrogenation

Mi Yeon Byun^{1, 2}, and Man Sig Lee^{1, 3, †}

¹Ulsan Division, Korea Institute of Industrial Technology (KITECH), Ulsan 44413, South Korea
²School of Chemical and Biomolecular Engineering, Pusan National University, Busan 46241, South Korea
³Department of Green Process and System Engineering, University of Science and Technology (UST), Ulsan 44413, South Korea

E-mail:

Hierarchical porous carbon (HPC) was prepared using colloidal silica of different sizes as a template, and used as a support for Pt nanoparticles. The Pt dispersion varied with the pore size and structure of the HPC supports. However, the measured Pt dispersions (70%-76%) suggested that this characteristic was not affected by the pore size distribution above a certain size. The activities of the prepared Pt/HPC catalysts for furfural hydrogenation were then investigated. The HPC supports with large pores allowed for greater contact between the Pt nanoparticles and reactants due to the high mass transfer rate, resulting in the highest furfural conversion and 1-pentanol selectivity. In contrast, the HPC supports with small pores exhibited higher furfuryl alcohol selectivities. The effect of the solvent on furfural hydrogenation was also investigated, and it was found that the solubility of H2 in the solvent affected the furfural conversion and product selectivity.

Keywords:Furfural;Hydrogenation;Hierarchical porous carbon;1-pentanol;Pt nanoparticles

[References]

Isikgor FH, Becer CR, Polym. Chem., 6(25), 4497 (2015)
Limayem A, Ricke SC, Prog. Energy Combust. Sci., 38(4), 449 (2012)
Fukuoka A, Dhepe PL, Angew. Chem.-Int. Edit., 45, 5161 (2006)
Merlo AB, Vetere V, Ruggera JF, Casella ML, Catal. Commun., 1665 (2009).
Li C, Xu GY, Liu XH, Zhang Y, Fu Y, Ind. Eng. Chem. Res., 56(31), 8843 (2017)
Date NS, Hengne AM, Huang KW, Chikate RC, Rode CV, Green Chem., 20(9), 2027 (2018)
Yilmaz N, Atmanli A, Trujillo M, Fuel, 207, 461 (2017)
Li L, Wang JX, Wang Z, Liu HY, Energy, 80, 575 (2015)
Cann AF, Liao JC, Appl. Microbiol. Biotechnol., 85(4), 893 (2010)
Bhogeswararao S, Srinivas D, J. Catal., 327, 65 (2015)
Xu L, Nie R, Lyu X, Wang J, Lu X, Fuel Process. Technol., 197 (2020)
Date NS, Kondawar SE, Chikate RC, Rode CV, ACS Omega, 3(8), 9860 (2018)
Song WJ, Yi XD, Jiang XM, Lai WK, Ind. Eng. Chem. Res., 59(46), 20298 (2020)
Hu J, Zhang Z, Wang F, Zheng S, Cai J, Qin J, Liu W, Liang S, Jiang X, RSC Adv., 6(103), 101544 (2016)
Yu ZJ, Zhang LJ, Zhang ZM, Zhang S, Hu S, Xiang J, Wang Y, Liu Q, Liu QH, Hu X, Int. J. Hydrog. Energy, 45(4), 2720 (2020)
Lee J, Woo J, Nguyen-Huy C, Lee MS, Joo SH, An K, Catal. Today, 350, 71 (2020)
Wang Z, Kiesel ER, Stein A, J. Mater. Chem., 18(19), 2194 (2018)
Guo N, Li M, Sun X, Wang F, Yang R, Green Chem., 19(11), 2595 (2017)
Ban C, Yang S, Kim H, Kim DH, Catal. Today, 352, 66 (2020)
Zhang T, Souza IPAF, Xu J, Almeida VC, Asefa T, Nanomaterials, 8, 9 (2018)
Shukla AK, Arico AS, El-Khatib KM, Kim H, Antonucci PL, Antonucci V, Appl. Surf. Sci., 137, 20 (1999)
Siburian R, Ali AMM, Sebayang K, Supeno M, Tarigan K, Simanjuntak C, Aritonang SP, Hutagalung F, Sci. Rep., 11(1), 1 (2021)
Liu LJ, Lou H, Chen M, Appl. Catal. A: Gen., 550, 1 (2018)
Zhao X, Zhu J, Liang L, Liao J, Liu C, Xing W, J. Mater. Chem., 22, 37 (2012)
Yi Z, Xu H, Hu D, Yan K, J. Alloy. Compd., 799, 59 (2019)
Seemala B, Kumar R, Cai CM, Wyman CE, Christopher P, React. Chem. Eng., 4(2), 261 (2019)
Yan K, Wu G, Lafleur T, Jarvis C, Renew. Sust. Energ. Rev., 38, 663 (2014)
Dimas-Rivera GL, De la Rosa JR, Lucio-Ortiz CJ, Martinez-Vargas DX, Sandoval-Rangel L, Gutierrez DIG, Maldonado CS, Appl. Catal. A: Gen., 543, 133 (2017)
Fu ZL, Wang Z, Lin WG, Song WL, Li SG, Appl. Catal. A: Gen., 547, 248 (2017)
Wang G, Yao R, Xin H, Guan Y, Wu P, Li X, RSC Adv., 8(65), 37243 (2018)
Yoshida H, Onodera Y, Fujita SI, Kawamori H, Arai M, Green Chem., 17(3), 1877 (2015)
Gao X, Tian S, Jin Y, Wan X, Zhou C, Chen R, Dai Y, Yang Y, ACS Sustain. Chem. Eng., 8(33), 12722 (2020)
Hronec M, Fulajtarova K, Catal. Commun., 24, 100 (2012)
Zhang Q, Li SS, Zhu MM, Liu YM, He HY, Cao Y, Green Chem., 18(8), 2507 (2016)
Panagiotopoulou P, Martin N, Vlachos DG, J. Mol. Catal. A-Chem., 392, 223 (2014)
Srivastava S, Jadeja GC, Parikh J, RSC Adv., 6(2), 1649 (2016)
Wilson L, J. Am. Chem. Soc., 70, 1313 (1948)
Gebresillase MN, Shavi R, Seo JG, Green Chem., 20(22), 5133 (2018)
Figueredo AL, Costa CS, Gothe ML, Rossi LM, Bazito RC, Vidinha P, Pereira CG, Catal. Lett., 151(6), 1821 (2021)
Merlo AB, Vetere V, Ramallo-Lopez JM, Requejo FG, Casella ML, React. Kinet. Mech. Catal., 104(2), 467 (2011)

[1] Isikgor FH, Becer CR, Polym. Chem., 6(25), 4497 (2015)

[2] Limayem A, Ricke SC, Prog. Energy Combust. Sci., 38(4), 449 (2012)

[3] Fukuoka A, Dhepe PL, Angew. Chem.-Int. Edit., 45, 5161 (2006)

[4] Merlo AB, Vetere V, Ruggera JF, Casella ML, Catal. Commun., 1665 (2009).

[5] Li C, Xu GY, Liu XH, Zhang Y, Fu Y, Ind. Eng. Chem. Res., 56(31), 8843 (2017)

[6] Date NS, Hengne AM, Huang KW, Chikate RC, Rode CV, Green Chem., 20(9), 2027 (2018)

[7] Yilmaz N, Atmanli A, Trujillo M, Fuel, 207, 461 (2017)

[8] Li L, Wang JX, Wang Z, Liu HY, Energy, 80, 575 (2015)

[9] Cann AF, Liao JC, Appl. Microbiol. Biotechnol., 85(4), 893 (2010)

[10] Bhogeswararao S, Srinivas D, J. Catal., 327, 65 (2015)

[11] Xu L, Nie R, Lyu X, Wang J, Lu X, Fuel Process. Technol., 197 (2020)

[12] Date NS, Kondawar SE, Chikate RC, Rode CV, ACS Omega, 3(8), 9860 (2018)

[13] Song WJ, Yi XD, Jiang XM, Lai WK, Ind. Eng. Chem. Res., 59(46), 20298 (2020)

[14] Hu J, Zhang Z, Wang F, Zheng S, Cai J, Qin J, Liu W, Liang S, Jiang X, RSC Adv., 6(103), 101544 (2016)

[15] Yu ZJ, Zhang LJ, Zhang ZM, Zhang S, Hu S, Xiang J, Wang Y, Liu Q, Liu QH, Hu X, Int. J. Hydrog. Energy, 45(4), 2720 (2020)

[16] Lee J, Woo J, Nguyen-Huy C, Lee MS, Joo SH, An K, Catal. Today, 350, 71 (2020)

[17] Wang Z, Kiesel ER, Stein A, J. Mater. Chem., 18(19), 2194 (2018)

[18] Guo N, Li M, Sun X, Wang F, Yang R, Green Chem., 19(11), 2595 (2017)

[19] Ban C, Yang S, Kim H, Kim DH, Catal. Today, 352, 66 (2020)

[20] Zhang T, Souza IPAF, Xu J, Almeida VC, Asefa T, Nanomaterials, 8, 9 (2018)

[21] Shukla AK, Arico AS, El-Khatib KM, Kim H, Antonucci PL, Antonucci V, Appl. Surf. Sci., 137, 20 (1999)

[22] Siburian R, Ali AMM, Sebayang K, Supeno M, Tarigan K, Simanjuntak C, Aritonang SP, Hutagalung F, Sci. Rep., 11(1), 1 (2021)

[23] Liu LJ, Lou H, Chen M, Appl. Catal. A: Gen., 550, 1 (2018)

[24] Zhao X, Zhu J, Liang L, Liao J, Liu C, Xing W, J. Mater. Chem., 22, 37 (2012)

[25] Yi Z, Xu H, Hu D, Yan K, J. Alloy. Compd., 799, 59 (2019)

[26] Seemala B, Kumar R, Cai CM, Wyman CE, Christopher P, React. Chem. Eng., 4(2), 261 (2019)

[27] Yan K, Wu G, Lafleur T, Jarvis C, Renew. Sust. Energ. Rev., 38, 663 (2014)

[28] Dimas-Rivera GL, De la Rosa JR, Lucio-Ortiz CJ, Martinez-Vargas DX, Sandoval-Rangel L, Gutierrez DIG, Maldonado CS, Appl. Catal. A: Gen., 543, 133 (2017)

[29] Fu ZL, Wang Z, Lin WG, Song WL, Li SG, Appl. Catal. A: Gen., 547, 248 (2017)

[30] Wang G, Yao R, Xin H, Guan Y, Wu P, Li X, RSC Adv., 8(65), 37243 (2018)

[31] Yoshida H, Onodera Y, Fujita SI, Kawamori H, Arai M, Green Chem., 17(3), 1877 (2015)

[32] Gao X, Tian S, Jin Y, Wan X, Zhou C, Chen R, Dai Y, Yang Y, ACS Sustain. Chem. Eng., 8(33), 12722 (2020)

[33] Hronec M, Fulajtarova K, Catal. Commun., 24, 100 (2012)

[34] Zhang Q, Li SS, Zhu MM, Liu YM, He HY, Cao Y, Green Chem., 18(8), 2507 (2016)

[35] Panagiotopoulou P, Martin N, Vlachos DG, J. Mol. Catal. A-Chem., 392, 223 (2014)

[36] Srivastava S, Jadeja GC, Parikh J, RSC Adv., 6(2), 1649 (2016)

[37] Wilson L, J. Am. Chem. Soc., 70, 1313 (1948)

[38] Gebresillase MN, Shavi R, Seo JG, Green Chem., 20(22), 5133 (2018)

[39] Figueredo AL, Costa CS, Gothe ML, Rossi LM, Bazito RC, Vidinha P, Pereira CG, Catal. Lett., 151(6), 1821 (2021)

[40] Merlo AB, Vetere V, Ramallo-Lopez JM, Requejo FG, Casella ML, React. Kinet. Mech. Catal., 104(2), 467 (2011)