화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.104, 529-543, December, 2021
DOI10.1016/j.jiec.2021.09.005  Export Citation
N-functionalized mesoporous carbon supported Pd nanoparticles as highly active nanocatalyst for Suzuki-Miyaura reaction, reduction of 4-nitrophenol and hydrodechlorination of chlorobenzene
Juti Rani Deka, Diganta Saikia1, Po-Hung Chen1, Ke-Ting Chen1, Hsien-Ming Kao1, †, and Yung-Chin Yang†
  • Institute of Materials Science and Engineering, National Taipei University of Technology, Taipei 106, Taiwan, ROC
  • 1Department of Chemistry, National Central University, Chung-Li 32054, Taiwan, ROC
E-mail:,
A series of nanocatalysts derived from immobilization of palladium nanoparticles (Pd NPs) into three dimensional (3D) tube-type architecture of nitrogen (N) functionalized and without functionalized mesoporous carbon CMK-9 is developed by dual agents chemical reduction approach. Herein, for the first time N-functionalized CMK-9 is explored as supports to immobilize Pd NPs and use as multifunctional catalysts for Suzuki-Miyaura cross-coupling reaction, reduction of 4-nitrophenol and hydrodechlorination of chlorobenzene. The Pd@N-CMK-9 catalysts show excellent activities with 100% conversion for Suzuki-Miyaura reaction between iodobenzene and phenylboronic acid and turnover frequency up to 1992 h-1. When use as catalyst for reduction of 4-nitrophenol to 4-aminophenol, it delivers an outstanding rate constant of 4.22 x 10-2 s-1 with activity parameter of 51719 s-1g-1 with respect to only Pd content. The nanocatalysts also demonstrate 100% conversion of chlorobenzene to benzene within 1 h. In addition, the catalyst exhibits remarkable catalytic stability for several cycles without any significant loss of products. The excellent catalytic activities can be attributed to synergistic effect of uniformly dispersed Pd NPs, favorable interaction between metal and support, and tubular interconnected mesoporous framework of N-functionalized CMK-9 that accelerate mass transportation. The present work signifies the versatility of Pd@N-CMK-9 nanocatalysts for various catalytic reactions.
Keywords:Mesoporous carbon;Pd nanoparticles;Suzuki-Miyaura cross-coupling;4-nitrophenol;Hydrodechlorination
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