화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.105, 121-131, January, 2022
DOI10.1016/j.jiec.2021.09.015  Export Citation
Neryl acetate synthesis from nerol esterification with acetic anhydride by heterogeneous catalysis using ion exchange resin
Rubieli Carla Frezza Zeferino1, 2, †, Vinicius Aleixo Angonese Piaia2, Vinícius Tres Orso2, Vítor Machado Pinheiro2, Micheli Zanetti2, 3, Gustavo Lopes Colpani2, 3, Natan Padoin1, Cíntia Soares1, Márcio Antônio Fiori1, 2, and Humberto Gracher Riella1
  • 1Graduate Program in Chemical Engineering, Department of Chemical and Food Engineering,, Federal University of Santa Catarina (UFSC), Florianópolis 88040-900, SC, Brazil
  • 2Department of Chemical and Food Engineering, Community University of Chapecó Region (UNOCHAPECÓ), Chapecó 89809-900, SC, Brazil
  • 3Post-Graduate Program in Technology and Innovation Management, Department of Chemical Engineering and Food Engineering, Community University of Chapecó Region (UNOCHAPECÓ), Chapecó 89809-900, SC, Brazil
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This work aims to synthesize neryl acetate from the nerol esterification reaction with acetic anhydride through heterogeneous catalysis using the ion exchange resin Lewatit® GF 101. The reaction was monitored by gas chromatography and the neryl acetate chemical structure was confirmed by mass spectrometry and nuclear magnetic resonance spectroscopy. The variables effect on the neryl acetate synthesis was evaluated from an experimental design analysis. The reaction showed the highest combined values for nerol conversion (98.11%) and neryl acetate selectivity (86.10%) at 30 min within optimal experimental conditions of temperature at 40 °C, catalyst content at 7% wt, molar ratio at 1:4 (nerol: acetic anhydride), agitation speed at 250 rpm and nerol content at 3 mmol. The complete nerol conversion was achieved at 40 min with 82.34% selectivity. The reaction rate was controlled only by the nerol decay, an expected behavior due to the excess of acetic anhydride used. In addition, the value obtained for the main reaction kinetic constant found by a pseudo-homogeneous model was 6 times greater than that of the parallel reaction. The catalyst reuse was investigated and after 3 cycles a high conversion (96.68%) and selectivity (83.78%) were observed indicating a low loss of the catalytic activity.
Keywords:Neryl acetate;Esterification reaction;Heterogeneous catalysis;Ion exchange resin;Kinetic model;Reaction mechanism
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