화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.105, 171-180, January, 2022
DOI10.1016/j.jiec.2021.09.019  Export Citation
VOx-MoOy single molecular layer modified graphic carbon nitride polymer for enhanced selective styrene oxidation
Xinrui Jing, Hongxia Wang, Songnan Li, Bin Lu, Jingxiang Zhao, and Qinghai Cai†
  • Key Lab for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Harbin Normal University, No. 1 Shida Road Limin Development Zone, Harbin 150025, PR China
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Graphic carbon nitride polymer was modified with transition bimetals compounds by impregnation of pre-prepared g-C3N4 in aqueous solution of ammonium molybdate and vanadate. The prepared hybrid material was characterized by XRD, SEM, TEM, FT-IR, XPS and N2 adsorption.desorption techniques to determine its surface morphology, composition and structure. The results revealed that VOx-MoOy single molecular layer incorporated into g-C3N4 molecule framework by interaction between host and guest was fabricated. The hybrid composite was employed as catalyst for styrene oxidation to benzaldehyde using molecular oxygen as oxidant. The results indicated that the composite was highly active and selective for styrene oxidation, giving TON 458.8 mol/mol(Mo+V) and 96.7% selectivity to benzaldehyde. The correlation between high activity and surface properties the catalyst was explored.
Keywords:Styrene;Selective oxidation;VOx-MoOy single molecular layer modified;g-C3N4;Benzaldehyde
  1. Che CM, Huang JS, Chem. Commun., 3996 (2009).
  2. Sorokin A, Seris JL, Meunier B, Science, 268(5214), 1163 (1995)
  3. Jacobsen EN, Zhang W, Guler ML, J. Am. Chem. Soc., 113, 6703 (1991)
  4. Xia QH, Ge HQ, Ye CP, Liu ZM, Su KX, Chem. Rev., 105(5), 1603 (2005)
  5. Vankelecom IFJ, Tas D, Parton RF, de Vyver VV, Jacobs PA, Chem. Int. Ed., 35, 1346 (1996)
  6. Zhang JL, Liu YL, Che CM, Chem. Commun., 2906 (2002).
  7. Pu L, Chem. Rev., 98(7), 2405 (1998)
  8. Wang X, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson JM, Domen K, Antonietti M, Nature Mater., 8, 76 (2009)
  9. Zhao Z, Sun Y, Dong F, Nanoscale, 7, 15 (2015)
  10. Li Z, Wang J, Zhu K, Ma F, Meng A, Mater. Lett., 145, 167 (2015)
  11. Yang Z, Li J, Cheng F, Chen Z, Dong X, J. Alloy. Compd., 634, 215 (2015)
  12. He Y, Wang Y, Zhang L, Teng B, Fan M, Appl. Catal. B: Environ., 168-169, 1 (2015)
  13. Cai Q, Shen J, Feng Y, Shen Q, Yang H, J. Alloy. Compd., 628, 372 (2015)
  14. Ding Z, Chen X, Antonietti M, Wang X, ChemSusChem, 4, 274 (2011)
  15. Wang XC, Chen XF, Thomas A, Fu XZ, Antonietti M, Adv. Mater., 21(16), 1609 (2009)
  16. Sudhaik A, Raizada P, Shandilya P, Jeong DY, Lim JH, Singh P, J. Ind. Eng. Chem., 67, 28 (2018)
  17. Nithya JSM, Do JY, Kang MS, J. Ind. Eng. Chem., 57, 405 (2018)
  18. Wang Y, Zhang J, Wang X, Antonietti M, Li H, Angew. Chem.-Int. Edit., 49, 3356 (2010)
  19. Zhang P, Li H, Wang Y, Chem. Commun., 50, 6312 (2014)
  20. Zhang P, Gong Y, Li H, Chen Z, Wang Y, RSC Adv., 3, 5121 (2013)
  21. Ma H, Wang H, Lu B, Zhao J, Mol. Catal., 469, 45 (2019)
  22. Zhang J, Wang H, Lu B, Zhao J, Cai Q, Catal. Lett. (2020)
  23. Martin DJ, Qiu KP, Shevlin SA, Handoko AD, Chen XW, Guo ZX, Tang JW, Angew. Chem.-Int. Edit., 53, 9240 (2014)
  24. Chen J, Zhao D, Diao Z, Wang M, Guo L, Shen S, ACS Appl. Mater. Interfaces, 7, 18843 (2015)
  25. Li KX, Zeng ZX, Yana LS, Luo SL, Luo XB, Huo MX, Guo YH, Appl. Catal. B: Environ., 165, 428 (2015)
  26. Zhu Z, Lu ZY, Wang DD, Tang X, Yan YS, Shi WD, Wang YS, Gao NL, Yao X, Dong HJ, Appl. Catal. B: Environ., 182, 115 (2016)
  27. Gibot P, Schnell F, Spitzer D, Microporous Mesoporous Mater., 219, 42 (2016)
  28. Song JM, Ni XM, Gao LS, Zheng HG, Mater. Chem. Phys., 102(2-3), 245 (2007)
  29. Wongkrua P, Thongtem T, Thongtem S, J. Nanomater., 2013 (2013)
  30. Li YF, Fang L, Jin RX, Yang Y, Fang X, Xing Y, Song SY, Nanoscale, 7, 758 (2015)
  31. Cheng NY, Tian JQ, Liu Q, Ge CJ, Qusti AH, Asiri AM, Al-Youbi AO, Sun XP, ACS Appl. Mater. Interfaces, 5, 6815 (2013)
  32. Raymundo-Pinero E, Cazorla-Amoros D, Linares-Solano A, Find J, Wild U, Schlogl R, Carbon, 40, 597 (2002)
  33. Han J, Meeprasert J, Maitarad P, Nammuangruk S, Shi L, Zhang D, J. Phys. Chem. C, 120, 1523 (2016)
  34. Xue S, Zhang W, Zhang Q, Du J, Cheng H, Ren W, Carbon, 165, 122 (2020)
  35. Chin YH, Iglesia E, J. Phys. Chem. C, 115, 17845 (2011)
  36. Tu W, Chin YH, Angew. Chem.-Int. Edit., 53, 12148 (2014)
  37. Rak MJ, Lerro M, Moores A, Chem. Commun., 50, 12482 (2014)
  38. Wang L, Zhang B, Zhang GW, Zhang J, Gao X, Meng X, Su D, Xiao F, Chem. Commun., 49, 3449 (2013)
  39. Lin YH, Williams ID, Li P, Appl. Catal. A: Gen., 150(2), 221 (1997)
  40. Farrag M, J. Mol. Catal. A-Chem., 413, 67 (2016)
  41. Fu YH, Xu L, Shen HM, Yang H, Zhang FM, Zhu WD, Fan MH, Chem. Eng. J., 299, 135 (2016)
  42. Nie L, Xin KK, Li WS, Zhou XP, Catal. Commun., 8, 488 (2007)
  43. Liu J, Wang Z, Jian P, Jian R, J. Colloid Interface Sci., 17, 144 (2018)
  44. Jin WQ, Wang HX, Lu B, Zhao JX, Cai QH, Ind. Eng. Chem. Res., 59(10), 4411 (2020)
  45. Xie L, Wang H, Lu B, Zhao J, Cai Q, React. Kinet. Mech. Catal., 125, 743 (2018)
  46. Pathan S, Patel A, Ind. Eng. Chem. Res., 52(34), 11913 (2013)