Journal of Industrial and Engineering Chemistry, Vol.105, 291-302, January, 2022
Construction of bifunctionalized Co-V mixed metal oxide nanosheets with Co3+-Rich surfaces and oxygen defect derived from LDHs as nanozyme for antibacterial application
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With the rapid development of multiple functional nanozymes, the research on the unique characteristic, contributing to the enzyme-like activity, is essential for us to construct mimic enzymes with outstanding activity. Herein, 2D Co-V mixed metal oxides (MMOs) are prepared through Co-V layered double hydroxide (LDH) precursor. The single phase of Co-V LDHs is prepared by controlling the dosage of hexamethylenetetramine accurately in the coprecipitation system. After calcinated at 400 °C, the obtained Co-V MMOs, composed of Co3V2O8 and Co3O4, still inherite the microtopography of nanosheets from the precursor, which have superior surface properties to enhance the peroxidase/oxidase (POD/OXD)-like activity. 2D Co-V MMO nanosheets have excellent bactericidal properties in the presence of H2O2 as low as 1 μM. The enhanced catalytic performances are attributed to unique hybrid nanosheets architecture and synergistic effect of two active components, ranking the hybrid nanostructure as a promising
antibacterial material.
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