화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.105, 491-501, January, 2022
DOI10.1016/j.jiec.2021.10.011  Export Citation
Sulfur dioxide absorption characteristics of aqueous amino acid solutions
Kwanghwi Kim1, 2, Hyun Sic Park1, Hyunji Lim1, 2, Jo Hong Kang1, Jinwon Park2, and Hojun Song1, †
  • 1Green Materials & Processes R&D Group, Korea Institute of Industrial Technology, 55 Jongga-ro, Jung-gu, Ulsan 44413, South Korea
  • 2Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, South Korea
E-mail:
The SO2 absorption/desorption performances of 14 aqueous amino acid solutions were evaluated to identify efficient absorbents to remove SO2 from coal-powered plant emissions. SO2 absorption/desorption experiments were conducted at 298.15 and 373.15 K, respectively, using 600 ppmv SO2 (N2 balance) and N2 purging. Thereafter, the absorption/desorption loadings and rates of the solutions, as well as their net cyclic capacities, were compared. The SO2 absorption mechanisms were explored via 13C NMR, 1H NMR, and UV-Vis analyses, and the relationship between the pKa values and absorption performances of the 14 aqueous amino acid solutions was investigated. Furthermore, the effects of absorption temperature, absorbent concentration, and inlet SO2 concentration on the SO2 absorption performances of the solutions were explored. 5-Aminovaleric acid, 4-aminobutyric acid, b-alanine, and histidine were identified as suitable SO2 absorbents based on their absorption/desorption performances and their net cyclic capacities. Furthermore, the net cyclic capacities of these four absorbents were similar or superior to those of previously reported deep eutectic solvents and ionic liquids. The results of this study provide a strategy for preparing eco-friendly SO2 absorbents.
Keywords:Sulfur dioxide removal;Flue gas desulfurization;Amino acid;Absorption;Desorption
  1. Wang L, Zhang Y, Liu Y, Xie H, Xu Y, Wei J, J. Hazard. Mater., 392 (2020)
  2. Park HS, Kang D, Kang JH, Kim K, Kim J, Song H, Int. J. Environ. Res. Public Health, 18, 597 (2021)
  3. Izquierdo JF, Fite C, Cunill F, Iborra M, Tejero J, J. Hazard. Mater., 76(1), 113 (2000)
  4. Dahlan I, Lee KT, Kamaruddin AH, Mohamed AR, J. Hazard. Mater., 161(1), 570 (2009)
  5. Moreno-Rios AL, Tejeda-Benitez LP, Bustillo-Lecompte CF, Geosci. Front. (2021).
  6. Meng XC, Wang JY, Xie PT, Jiang HC, Hu YQ, Chang T, Energy Fuels, 32(2), 1956 (2018)
  7. Arani MA, Hatamipour MS, Rahimi A, Ind. Eng. Chem. Res., 59(19), 8984 (2020)
  8. Zhang Z, Yang B, Ma H, Sep. Purif. Technol., 259 (2021)
  9. Zhang K, Ren SH, Meng LY, Hou YC, Wu WZ, Bao YY, Energy Fuels, 31(2), 1786 (2017)
  10. Li ZL, Zhou LS, Wei YH, Peng HL, Huang K, Ind. Eng. Chem. Res., 59(30), 13696 (2020)
  11. Newman W, Biggs E, Sulphur Dioxide Removal from Stack Gases a Review of Available Methods, Ontario Ministry of the Environment, 1975.
  12. Jiang B, Zhang H, Zhang L, Zhang N, Huang Z, Chen Y, Sun Y, Tantai X, A.C.S. Sustain. Chem. Eng., 7, 8347 (2019)
  13. Vandam MH, Lamine AS, Roizard D, Lochon P, Roizard C, Ind. Eng. Chem. Res., 36(11), 4628 (1997)
  14. Demyanovich RJ, Lynn S, J. Sol. Chem., 20, 693 (1991)
  15. Tang ZG, Zhou CC, Chen C, Ind. Eng. Chem. Res., 43(21), 6714 (2004)
  16. Vo HT, Cho SH, Lee U, Jae JH, Kim HG, Lee HJ, J. Ind. Eng. Chem., 69, 338 (2019)
  17. Demyanovich RJ, Lynn S, Ind. Eng. Chem. Res., 26, 548 (1987)
  18. Zahiri MR, Roozbehani B, J. Mater. Environ. Sci., 9, 2587 (2018)
  19. Hong SY, Kim H, Kim YJ, Jeong J, Cheong M, Lee H, Kim HS, Lee JS, J. Hazard. Mater., 264, 136 (2014)
  20. Ren SH, Hou YC, Tian SD, Chen XM, Wu WZ, J. Phys. Chem. B, 117(8), 2482 (2013)
  21. Biczak R, Pawlowska B, Balczewski P, Rychter P, J. Hazard. Mater., 274, 181 (2014)
  22. Pham TPT, Cho CW, Yun YS, Water Res., 44, 352 (2010)
  23. Peric B, Sierra J, Marti E, Cruanas R, Garau MA, Arning J, Bottin-Weber U, Stolte S, J. Hazard. Mater., 261, 99 (2013)
  24. Paduszynski K, Domanska U, J. Chem. Inf. Model., 54, 1311 (2014)
  25. Maton C, De Vos N, Stevens CV, Chem. Soc. Rev., 42, 5963 (2013)
  26. Deng R, Jia L, Song Q, Su S, Tian Z, J. Hazard. Mater., 229-230, 398 (2012)
  27. Deng RP, Jia LS, Fuel, 93(1), 385 (2012)
  28. Hanif MA, Ibrahim N, Abdul Jalil A, Environ. Sci. Pollut. Res., 27, 27515 (2020)
  29. Goldberg RN, Kishore N, Lennen RM, J. Phys. Chem. Ref. Data, 31, 231 (2002)
  30. Qian JG, Ren SH, Tian SD, Hou YC, Wang CX, Wu WZ, Ind. Eng. Chem. Res., 53(39), 15207 (2014)
  31. Zhang K, Ren SH, Yang X, Hou YC, Wu W, Bao YY, Chem. Eng. J., 327, 128 (2017)
  32. Jiang B, Hou S, Zhang LH, Yang N, Zhang N, Xiao XM, Yang XD, Sun YL, Tantai XW, Ind. Eng. Chem. Res., 59(38), 16786 (2020)
  33. Kang S, Chung YG, Kang JH, Song H, J. Mol. Liq., 297 (2020)
  34. Song HJ, Park S, Kim H, Gaur A, Park JW, Lee SJ, Int. J. Greenhouse Gas Control, 11, 64 (2012)
  35. Park S, Song HJ, Lee MG, Park J, Korean J. Chem. Eng., 31, 125 (2013)
  36. Cui G, Liu J, Lyu S, Wang H, Li Z, Wang J, ACS Sustainable Chem. Eng., 7, 14236 (2019)
  37. Kumar S, Mondal MK, Korean J. Chem. Eng., 37(2), 231 (2020)
  38. Shen SF, Yang YN, Wang Y, Ren SF, Han JZ, Chen AB, Fluid Phase Equilib., 399, 40 (2015)
  39. Siddiqi MA, Krissmann J, Petersgerth P, Luckas M, Lucas K, J. Chem. Thermodyn., 28(7), 685 (1996)
  40. Shim JG, Jhon YH, Kim JH, Jang KR, Kim JH, Bull. Korean Chem. Soc., 28, 1609 (2007)
  41. Douglas JE, Kollman PA, J. Am. Chem. Soc., 100, 5226 (1978)
  42. Rumble JR, CRC Handbook of Chemistry and Physics, 100th ed., CRC Press, Boca Raton, United States, 2019.
  43. Ding F, He X, Luo X, Lin W, Chen K, Li H, Wang C, Chem. Commun., 50, 15041 (2014)
  44. Kim HS, Kim M, Cheong M, Proceedings of the World Congress on Civil, Structural, and Environmental Engineering, 2016.
  45. Qian J, Sun R, Sun SZ, Gao JH, J. Chem. Eng. Data, 62(1), 111 (2017)
  46. Rajan VK, Muraleedharan K, Int. J. Greenhouse Gas Control, 58, 62 (2017)
  47. Bernhardsen IM, Knuutila HK, Int. J. Greenh Gas Control, 61, 27 (2017)
  48. Vaidya PD, Kenig EY, Chem. Eng. Technol., 30, 1467 (2007)
  49. Idris Z, Eimer DA, Energy Procedia, 51, 247 (2014)
  50. Geng Z, Xie Q, Fan Z, Sun W, Zhao W, Zhang J, Chen J, Xu Y, J. Environ. Chem. Eng., 9 (2021)
  51. Zhang HM, Jiang B, Yang N, Zhang N, Zhang LH, Huang ZH, Xiao XM, Tantai XW, Energy Fuels, 33(9), 8937 (2019)
  52. Zhang XM, Feng X, Li H, Peng J, Wu YT, Hu XB, Ind. Eng. Chem. Res., 55(41), 11012 (2016)
  53. An D, Wu LB, Li BG, Zhu SP, Macromolecules, 40(9), 3388 (2007)
  54. Dupuit E, Dandrieux A, Kvapil P, Ollivier J, Dusserre G, Thomas O, Analusis, 28, 966 (2000)
  55. Yang Z, Zhang Y, Zhang Q, Pei T, Meng Z, Procedia Environ. Sci., 18, 92 (2013)
  56. Wright J, J. Chem. Soc. Trans., 105, 669 (1914)
  57. Saidel LJ, Goldfarb AR, Waldman S, J. Biol. Chem., 197, 285 (1952)
  58. Zhao Y, Dou J, Wei A, Khoshkrish S, Yu J, J. Mol. Liq., 340 (2021)
  59. Yang D, Zhang S, Jiang DE, ACS Sustainable Chem. Eng., 7, 9086 (2019)
  60. Li J, Kang Y, Li BH, Wang X, Li D, Energy Fuels, 32(12), 12703 (2018)
  61. Cui G, Zhang F, Zhou X, Huang Y, Xuan X, Wang J, ACS Sustainable Chem. Eng., 3, 2264 (2015)
  62. Chen KH, Lin WJ, Yu XN, Luo XY, Ding F, He X, Li HR, Wang CM, AIChE J., 61(6), 2028 (2015)
  63. Zhang K, Ren SH, Hou YC, Wu WZ, J. Hazard. Mater., 324, 457 (2017)
  64. Jin MJ, Hou YC, Wu WZ, Ren SH, Tian SD, Xiao L, Lei ZG, J. Phys. Chem. B, 115(20), 6585 (2011)
  65. Krzyzynska R, Hutson ND, J. Air Waste Manage. Assoc., 62, 707 (2012)
  66. Krzyzynska R, Hutson ND, J. Air Waste Manage. Assoc., 62, 212 (2012)
  67. Meng ZH, Wang CY, Wang XR, Chen Y, Li HQ, Energy Fuels, 32(2), 2028 (2018)