화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.39, No.1, 96-108, January, 2022
DOI10.1007/s11814-021-0844-y  Export Citation
Enhanced adsorptive-oxidative desulfurization of dibenzothiopheneover Ti-MWW using cumene hydroperoxide as oxidant
Xingye Zeng, Adeyemo Adesina, Ping Li1, Hanlu Wang†, and Rujin Zhou†
  • Key Laboratory of Inferior Crude Oil Processing of Guangdong Provincial Higher Education Institutes, Guangdong University of Petrochemical Technology, Maoming, 525000, P. R. China
  • 1Production Management Department, Sinopec Maoming Petrochemical Company, Maoming, 525000, P. R. China
E-mail:,
Ti-containing Mobil composition of matter-twenty-two (Ti-MWW) zeolite was prepared via a two-step post-synthesis process and then characterized by X-ray fluorescence, nitrogen adsorption-desorption isotherms, Fourier transform infrared absorption spectra, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectra. These results indicate that the textural properties of MWW were well preserved after acid treatment and incorporation of titanium. An adsorptive-oxidative desulfurization (AODS) system was successfully developed on the basis of a model oil containing dibenzothiophene (DBT) with the as-prepared Ti-MWW being the catalyst and adsorbent and cumene hydroperoxide (CHP) being the oxidant. The parameters influencing the desulfurization performance were systematically investigated. These parameters include the Ti-MWW dosage, the reaction temperature, the stirring speed, the molar ratio of CHP to DBT and the additions of olefins and aromatics to the system. The conversion rate of DBT reached 99.6% via the catalytic oxidation process and the turnover frequency was 40.1 h?1. Meanwhile, the oxidation products of DBT were removed by Ti-MWW adsorption. The recycling and regeneration performance of Ti-MWW were also investigated, and the DBT conversion reached 99.5% using the regenerated Ti-MWW. This work provides useful information for the construction of solvent-free oxidative desulfurization systems using a zeolite.
Keywords:Adsorptive-oxidative Desulfurization;Ti-MWW;Dibenzothiophene;Cumene Hydroperoxide
  1. Zhang L, Chen ZM, Zheng SF, Cai GR, Fu WQ, Tang TD, He MY, Ind. Eng. Chem. Res., 59(27), 12338 (2020)
  2. Al-Degs YS, El-Sheikh AH, Al Bakain RZ, Newman AP, Al-Ghouti MA, Energy Technol., 4, 679 (2016)
  3. Raj JJ, Magaret S, Pranesh M, Lethesh KC, Devi WC, Mutalib MIA, J. Clean Prod., 213, 989 (2019)
  4. Song Y, Yang D, Yu S, Teng X, Chang Z, Pan F, Bu X, Jiang Z, Wang B, Wang S, Cao X, Sep. Purif. Techol., 210, 258 (2019)
  5. Geng T, He J, Hu L, Li J, Inorg. Chem. Commun., 101, 103 (2019)
  6. Wen J, Zhao D, Lu Y, Huang J, Li Y, Zhang H, Li A, Korean J. Chem. Eng., 36(7), 1131 (2019)
  7. Gan MX, Yang GQ, Wang ZH, Sui XF, Hou Y, Energy Fuels, 34(1), 778 (2020)
  8. Rivoira LP, Ledesma BC, Juarez JM, Beltramone AR, Fuel, 226, 498 (2018)
  9. Dana M, Shahhosseini S, Sobati MA, Ansari AR, Asadollahzadeh M, Energy Fuels, 34(1), 1041 (2020)
  10. Yue D, Lei JH, Peng Y, Li JS, Du XD, Fuel, 226, 148 (2018)
  11. Rogosic M, Sander A, Kojic V, Vukovic JP, Fluid Phase Equilib., 412, 39 (2016)
  12. Palomeque-Santiago JF, Lopez-Medina R, Oviedo-Roa R, et al., Appl. Catal. B: Environ., 236, 323 (2018)
  13. Rezvani MA, Shaterian M, Akbarzadeh F, Khandan S, Chem. Eng. J., 333, 537 (2018)
  14. Yue D, Lei JH, Zhou LN, Guo ZR, Du XD, Li JS, Catal. Lett., 148(4), 1100 (2018)
  15. Bazyari A, Khodadadi AA, Mamaghani AH, Beheshtian J, Thompson LT, Mortazavi Y, Appl. Catal. B: Environ., 180, 65 (2016)
  16. Zhou Q, Fu S, Zou M, He Y, Wu Y, Wu T, RSC Adv., 5, 69388 (2015)
  17. Abdullah WNW, Abu Bakar WAW, Ali R, Embong Z, Clean Technol. Environ., 17, 433 (2015)
  18. Yang CP, Zhao K, Cheng Y, Zeng GM, Zhang MM, Shao JJ, Lu L, Sep. Purif. Technol., 163, 153 (2016)
  19. Lin X, Zeng X, Zhou R, Wang H, React. Kinet. Mech. Cat., 126, 353 (2019)
  20. Shen C, Wang YJ, Xu JH, Luo GS, Chem. Eng. J., 259, 552 (2015)
  21. Chen Y, Song HY, Lu YZ, Meng H, Li CX, Lei ZG, Chen BH, Ind. Eng. Chem. Res., 55(39), 10394 (2016)
  22. Ostroumova VA, Maksimov AL, Petrol. Chem., 59, 788 (2019)
  23. Grzybek J, Roth WJ, Gil B, Korzeniowska A, Mazur M, Cejka J, Morris RE, J. Mater. Chem. A, 7, 7701 (2019)
  24. Zhang YY, Kubu M, Mazur M, Cejka J, Catal. Today, 324, 135 (2019)
  25. Wang H, Jibrin I, Zeng X, Front. Chem. Sci. Eng., 14, 546 (2020)
  26. Yin J, Xu H, Wang B, Tian W, Yin J, Jiang J, Wu P, Catal. Sci. Technol., 10, 6050 (2020)
  27. Gawarecka A, Wroblewska A, React. Kinet. Mech. Cat., 124, 523 (2018)
  28. Zhu M, Liu Y, Yao Y, Jiang J, Zhang F, Yang Z, Lu Z, Kumakiri I, Chen X, Kita H, Microporous Mesoporous Mater., 268, 84 (2018)
  29. Wang H, Yu M, Lin Z, J. Mol. Model., 25, 106 (2019)
  30. Du S, Chen X, Sun Q, Wang N, Jia M, Valtchev V, Yu J, Chem. Commun., 52, 3580 (2016)
  31. Du Q, Guo YP, Duan HN, Li H, Chen YJ, Liu HZ, Fuel, 188, 232 (2017)
  32. Leng KY, Sun YY, Zhang X, Yu M, Xu W, Fuel, 174, 9 (2016)
  33. Arellano U, Wang JA, Chen LF, Cao GZ, Asomoza M, Cipagauta S, J. Mol. Catal. A-Chem., 421, 66 (2016)
  34. Wamf F, Wang G, Bing L, Wang Y, Tian A, Yi K, Int. J. Chem. React. Eng., 16, 201701 (2018)
  35. Shi C, Wang W, Liu N, Xu X, Wang D, Zhang M, Sun P, Chen T, Chem. Commun., 51, 11500 (2015)
  36. Tang B, Dai W, Sun X, Guan N, Li L, Hunger M, Green Chem., 16, 2281 (2014)
  37. Yan MH, Jin F, Ding YG, Wu GY, Chen R, Wang LH, Yan YZ, Ind. Eng. Chem. Res., 58(12), 4764 (2019)
  38. Lu P, Gomez-Hortiguela L, Camblor MA, Chem-Eur. J., 25, 1561 (2019)
  39. Li B, Wu N, Wu K, Liu J, Han C, Li X, RSC Adv., 5, 16598 (2015)
  40. Wu L, Deng X, Zhao S, Yin H, Zhuo Z, Fang X, Liu Y, He M, Chem. Commun., 52, 8679 (2016)
  41. Wang J, Zhang F, Hua W, Yue Y, Gao Z, Catal. Commun., 18, 63 (2012)
  42. Leng K, Li X, Ye G, Du Y, Sun Y, Xu W, Catal. Sci. Technol., 6, 7615 (2016)
  43. Bazyari A, Khodadadi AA, Mamaghani AH, Beheshtian J, Thompson LT, Mortazavi Y, Appl. Catal. B: Environ., 180, 65 (2016)
  44. Tang B, Dai W, Sun X, Guan N, Li L, Hunger M, Green Chem., 16, 2281 (2014)
  45. Du Q, Guo Y, Wu P, Liu H, Chen Y, Microporous Mesoporous Mater., 275, 61 (2019)
  46. Gao Y, Lv ZY, Gao RM, Zhang G, Zheng Y, Zhao JS, J. Hazard. Mater., 359, 258 (2018)
  47. Li Z, Cui YN, Li CP, Shen YM, Sep. Purif. Technol., 219, 9 (2019)
  48. Li LT, Zhang JS, Shen C, Wang YJ, Luo GS, Fuel, 167, 9 (2016)
  49. Shen C, Wang YJ, Xu JH, Luo GS, Chem. Eng. J., 259, 552 (2015)
  50. Luna MDGd, Smaniego ML, Ong DC, Wan MW, Lu MC, J. Clean Prod., 178, 468 (2018)
  51. Lv Q, Li G, Sun HY, Fuel, 130, 70 (2014)
  52. Fang Y, Hu H, Catal. Commun., 8, 817 (2007)
  53. Yang ST, Jeong KE, Jeong SY, Ahn WS, Mater. Res. Bull., 47(12), 4398 (2012)
  54. Du S, Li F, Sun Q, Wang N, Jia M, Yu J, Chem. Commun., 52, 3368 (2016)
  55. Du S, Sun Q, Wang N, Chen X, Ji X, Yu J, J. Mater. Chem. A, 5, 7992 (2017)
  56. Du Q, Guo Y, Wu P, Liu H, Microporous Mesoporous Mater., 264, 272 (2018)
  57. Hulea V, Fajula F, Bousquet J, J. Catal., 198(2), 179 (2001)
  58. Cui SH, Ma F, Wang YQ, React. Kinet. Catal. Lett., 92(1), 155 (2007)
  59. Jin C, Li G, Wang X, Wang Y, Zhao L, Sun D, Microporous Mesoporous Mater., 111, 236 (2008)
  60. Jin C, Li G, Wang X, Zhao L, Wang Y, Sun D, Top. Catal., 49, 118 (2008)
  61. Bian H, Zhang H, Li D, Duan Z, Zhang H, Zhang S, Xu B, Microporous Mesoporous Mater., 294, 109837 (2020)
  62. Cheng S, Liu Y, Gao J, Wang L, Liu X, Gao G, Wu P, He M, Chin. J. Catal., 27, 547 (2006)