화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.39, No.1, 209-215, January, 2022
DOI10.1007/s11814-021-0938-6  Export Citation
Nanocomposite design of graphene modified TiO2 for electrochemical sensing in phenol detection
Muhammad Nurdin†, Maulidiyah Maulidiyah, Abdul Haris Watoni, Armawansa Armawansa, La Ode Agus Salim, Zul Arham1, Dwiprayogo Wibowo2, Irwan Irwan, and Akrajas Ali Umar3
  • Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo, Kendari 93232 - Southeast Sulawesi, Indonesia
  • 1Department of Mathematics and Natural Sciences, Institute Agama Islam Negeri (IAIN), Kendari 93563 - Southeast Sulawesi, Indonesia
  • 2Department of Environmental Engineering, Universitas Muhammadiyah Kendari, Kendari 93127 - Southeast Sulawesi, Indonesia
  • 3Institute of Microengineering and Nanoelectronics, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia
E-mail:
This study is the stage of developing a phenol detection electrochemical sensor. Phenol is one of the organic pollutants harmful to human life and ecosystems. The development of this sensor was carried out by studying the use of TiO2 anatase as a modifier of graphene electrodes. The mass of TiO2 anatase was varied, while the mass of graphene and paraffin was fixed. The results showed that the TiO2 mass of 1.0 g was the best mass as a graphene electrode modifier. The use of this mass increases the oxidation current (Ipa) of phenol by 450 A, which is observed at an oxidation potential (Epa) of -0.30V. The presence of interfering ions such as K+, Fe2+, and OH? can decrease the measurement current. However, based on the %RSD value, it shows that the performance of TiO2-graphene is in a good category, where the %RSD value obtained is 0.6%. TiO2-graphene electrodes can be used repeatedly for 12 days. Overall, this work demonstrates the potential of TiO2-graphene electrodes as electrode candidates for electrochemical-based phenol sensors.
Keywords:Anatase TiO2;Electrochemical Sensor;Electrode Modifier;Graphene;Phenol
  1. Farzadkia M, Shahamat YD, Nasseri S, Mahvi AH, Gholami M, Shahryari A, J. Eng., 520929, 1 (2014)
  2. Shahamat YD, Farzadkia M, Nasseri S, Mahvi AH, Gholami M, Esrafili A, J. Environ. Heal. Sci. Eng., 12, 1 (2014)
  3. Pi Y, Li X, Xia Q, Wu J, Li Y, Xiao J, Li Z, Chem. Eng. J., 337, 351 (2017)
  4. Slamet SB, Rita A, Zulaina S, J. Teknol., 303 (2006).
  5. Zhang Y, Zhang M, Wei Q, Gao Y, Guo L, Al-Ghanim KA, Mahboob S, Zhang X, Sensors, 16, 535 (2016)
  6. Wibowo D, Ruslan, Maulidiyah, Nurdin M, IOP Conf. Ser. Mater. Sci. Eng., 267, 012007 (2017)
  7. Hikmawati, Watoni AH, Wibowo D, Maulidiyah, Nurdin M, IOP Conf. Ser. Mater. Sci. Eng., 267, 012005 (2017)
  8. Maulidiyah M, Azis T, Lindayani L, Wibowo D, Salim LOA, Aladin A, Nurdin M, J. Electrochem. Sci. Technol., 10, 394 (2019)
  9. Nurdin M, Maulidiyah M, Salim LOA, Muzakkar MZ, Umar AA, Microchem. J., 145, 756 (2018)
  10. Nurdin M, Prabowo OA, Arham Z, Wibowo D, Maulidiyah M, Saad SKM, Umar AA, Surf. Interfaces, 16, 108 (2019)
  11. Nurdin M, Arham Z, Rasyid J, Maulidiyah M, Mustapa F, Sosidi H, Ruslan R, Salim LOA, J. Phys. Conf. Ser., 1763, 012067 (2021)
  12. Khopkar SM, Basic concepts of analytical chemistry, New Age International (1998).
  13. Bard AJ, Faulkner LR, Electrochem. Methods, 2, 482 (2001)
  14. Wang X, Zhi L, Mullen K, Nano Lett., 8, 32 (2008)
  15. Nurdin M, Agusu L, Putra AAM, Maulidiyah M, Arham Z, Wibowo D, Muzakkar MZ, Umar AA, J. Phys. Chem. Solids, 131, 104 (2019)
  16. Nurdin M, Ramadhan LOAN, Darmawati D, Maulidiyah M, Wibowo D, J. Coat. Technol. Res., 15, 395 (2018)
  17. Maulidiyah, Azis T, Nurwahidah AT, Wibowo D, Nurdin M, Environ. Nanotechnology, Monit. Manag., 8, 103 (2017)
  18. Nurdin M, Zaeni A, Rammang ET, Maulidiyah M, Wibowo D, Anal. Bioanal. Electrochem., 9, 480 (2017)
  19. Natsir M, Putri YI, Wibowo D, et al., J. Inorg. Organomet. Polym. Mater., 31, 3378 (2021)
  20. Nurdin M, Maulidiyah, Watoni AH, Abdillah N, Wibowo D, Int. J. ChemTech Res., 9, 483 (2016)
  21. Nurdin M, Zaeni A, Maulidiyah, Natsir M, Bampe A, Wibowo D, Orient. J. Chem., 32, 2713 (2016)
  22. Tavakkoli N, Soltani N, Salavati H, Talakoub M, J. Taiwan Inst. Chem. Eng., 83, 50 (2018)
  23. Bakardjieva S, Subrt J, Stengl V, Dianez MJ, Sayagues MJ, Appl. Catal. B: Environ., 58(3-4), 193 (2005)
  24. Tashkhourian J, Ana SFN, Hashemnia S, Hormozi-Nezhad MR, J. Solid State Electrochem., 17, 157 (2013)
  25. Srinivasu P, Singh SP, Islam A, Han L, Adv. Optoelectron., 539382, 1 (2011)
  26. Yasmin A, Luo JJ, Daniel IM, Compos. Sci. Technol., 66, 1179 (2006)
  27. Basheer C, J. Chem., 456586, 1 (2013)
  28. Wibowo D, Sufandy Y, Irwan I, Azis T, Maulidiyah M, Nurdin M, J. Mater. Sci. Mater. Electron., 28, 14375 (2020)
  29. Wang J, Analytical electrochemistry, John Wiley & Sons (2006).
  30. Ali Zolfigol M, Choghamarani AG, Phosphorus. Sulfur. Silicon Relat. Elem., 178, 1623 (2003).
  31. Nurdin M, Azis T, Maulidiyah M, Aladin A, Hafid NA, Salim LOA, Wibowo D, IOP Conf. Ser. Mater. Sci. Eng., 367, 012048 (2018)
  32. Maulidiyah M, Wijawan IBP, Wibowo D, Aladin A, Hamzah B, Nurdin M, IOP Conf. Ser. Mater. Sci. Eng., 367, 012060 (2018)
  33. Belkhamsa N, Ouattara L, Ksibi M, J. Electrochem. Soc., 162(8), B212 (2015)
  34. Buhlmann P, Pretsch E, Bakker E, Chem. Rev., 98, 1593 (1988)
  35. Bakker E, Buhlmann P, Pretsch E, Chem. Rev., 97(8), 3083 (1997)
  36. Maulidiyah, Tribawono DS, Wibowo D, Nurdin M, Anal. Bioanal. Electrochem., 8, 761 (2016)
  37. Wang JH, Cui W, Liu Q, Xing ZC, Asiri AM, Sun XP, Adv. Mater., 28(2), 215 (2016)
  38. Heng LY, Hall EAH, Anal. Chim. Acta, 443, 25 (2001)
  39. Mitsuyama T, Tsutsumi A, Hata T, Ikeue K, Machida M, Bull. Chem. Soc. Jpn., 81, 401 (2008)
  40. Criscenti LJ, Sverjensky DA, Am. J. Sci., 299, 828 (1999)