화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.106, 160-167, February, 2022
DOI10.1016/j.jiec.2021.10.022  Export Citation
A novel multiemissive Ln/covalent-organic frameworks for ratiometric detection of 2,6-dipicolinic acid
Lijuan Kuang, Yue Du, Shiqi Wang, Li Yang, and Yonghai Song†
  • Key Laboratory of Functional Small Organic Molecule, Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China
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As one of the specific biomarkers of anthrax, timely, sensitive and accurate detection of 2,6-dipicolinic acid (DPA) plays an important role in preventing biological weapons attacks and disease outbreaks. Here, multiemission Eu3+/covalent- organic framework (COFDTA-TFP) and Tb3+/COFDTA-TFP were constructed by the coordination between Eu3+ or Tb3+ with fluorescent COFDTA-TFP which was prepared by amine-aldehyde dehydration condensation between 2,5-diaminoterephthalic acid and 2,4,6- triformylphloroglucinol for the first time. The Eu3+/COFDTA-TFP and Tb3+/COFDTA-TFP can emit nonoverlapping fluorescence of COFDTA-TFP and Eu3+ or Tb3+, which was used to ratiometric detection of DPA. Due to the strong coordination between the nitrogen atoms in the pyridine ring and the oxygen atoms in the carboxyl group of DPA with Eu3+ or Tb3+, DPA replaced coordinated H2O to sensitize fluorescence of Eu3+ or Tb3+ by ‘‘antenna” effect but fluorescence of COFDTA-TFP with two-dimensional lamellar structure was kept constant as a reference. The linear range and detection limit of ratiometric fluorescence sensor based on Eu3+/COFDTA-TFP for detection of DPA are 0.01.12 mM and 4.2 nM, respectively. The linear range and detection limit of ratiometric fluorescence sensor based on Tb3+/COFDTA-TFP for detection of DPA are 0.01.9.0 μM and 2.9 nM, respectively.
Keywords:Covalent-organic framework;Lanthanide ions;2,6-Dipicolinic acid;Multiemission;Ratiometric fluorescence detection
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