Rational design of platinum assimilated 3-D zinc cobalt oxide flowers for the electrochemical detection of caffeine in beverage and energy drink

Antolin Jesila Jesu Amalraj; Umesh N.; Sea-Fue Wang

Journal of Industrial and Engineering Chemistry, Vol.106, 205-213, February, 2022

DOI10.1016/j.jiec.2021.10.026 Export Citation

Rational design of platinum assimilated 3-D zinc cobalt oxide flowers for the electrochemical detection of caffeine in beverage and energy drink

Antolin Jesila Jesu Amalraj, Umesh N., and Sea-Fue Wang^†

Department of Materials and Mineral Resources Engineering, National Taipei University of Technology, No. 1, 5 Section 3, Chung-Hsiao East Road, Taipei 106, Taiwan, ROC

E-mail:

In this work, platinum nanoparticles (Pt) decorated on a spinel group, zinc cobalt oxide (ZnCo2O4) 3-D flower was intended to detect caffeine electrochemical sensor. Pt particles were used to enhance the performance of hydrothermally prepared 3-D ZnCo2O4 flower. So Pt nanoparticles were decorated on each thin nanosheet of self-assembled 3-D flower-like ZnCo2O4. The thin transparent nanosheet of the ZnCo2O4 flower will benefit electrochemical sensors by simplifying its ion exchange. Therefore, Pt@ZnCo2O4 shows an excellent electrochemical conductivity, which promotes the caffeine-based sensor’s rapid electrochemical oxidation. Using amperometric i-t at an applied potential of 1.45 V, Pt@ZnCo2O4 modified electrode shows widespread of two linear ranges (0.05 to 265.55 μM and 295.55 to 757.55 μM) with a low detection limit (0.0114 and 0.01657 μM) and high sensitivity (3.419 and 1.862μlA μM-1 cm-2). Moreover, good results were obtained for the real-time detection of caffeine in sugar-free cola beverage and energy drink samples. Henceforth, the developed method could be an ideal way to detect caffeine in real samples.

Keywords:Spinel group ZnCo2O4;3-D flower-like structure;Caffeine sensor

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[2] Armenta S, Garrigues S, de la Guardia M, Anal. Chim. Acta, 547(2), 197 (2005)

[3] Zou J, Li N, J. Chromatogr. A, 1136(1), 106 (2006)

[4] Wang X, Wan X, Hu S, Pan C, Food Chem., 107(3), 1086 (2008)

[5] Sereshti H, Samadi S, Food Chem., 158, 8 (2014)

[6] Spataru N, Sarada BV, Tryk DA, Fujishima A, Electroanal. Int. J. Devoted Fundam. Pract. Asp. Electroanal., 14(11), 721 (2002)

[7] Pizzariello A, Svorc J, Stred��ansky M, Miertus S, J. Sci. Food Agric., 79(8), 1136 (1999)

[8] Jeevagan AJ, John SA, Electrochim. Acta, 77, 137 (2012)

[9] Svorc L, Int. J. Electrochem. Sci., 8, 5755 (2013)

[10] Sadok I, Tyszczuk-Rotko K, Nosal-Wiercin�� ska A, Sens. Actuat. B Chem., 235, 263 (2016)

[11] Peri-Okonny UL, Wang SX, Stubbs RJ, Guzman NA, Electrophoresis, 26(13), 2652 (2005)

[12] Chen Q, Guo Z, Zhao J, J. Pharm. Biomed. Anal., 48(5), 2008 (1321)

[13] Alpdogan G, Karabina K, Sungur S, Turk. J. Chem., 26(2), 295 (2002)

[14] Ch?vez JL, Lyon W, Kelley-Loughnane N, Stone MO, Biosens. Bioelectron., 26(1), 23 (2010)

[15] Kunugi A, Tabei K, J. High Resolut. Chromatogr., 20(8), 456 (1997)

[16] Zou J, Zhang H, Ding M, Shang Z, J. Zou, H. Zhang, M. Ding, Z. Shang, Chromatographia, 71(3), 323 (2010)

[17] Aranda M, Morlock G, J. Chromatogr. Sci., 45(5), 251 (2007)

[18] Arinobu T, Hattori H, Kumazawa T, Lee XP, Mizutani Y, Katase T, Kojima S, Omori T, Kaneko R, Ishii A, Forensic Toxicol., 27(1), 1 (2009)

[19] Rawat A, Chandra S, Sarkar A, Anal. Bioanal. Chem., 2, 212 (2010)

[20] Xiong XQ, Huang KJ, Xu CX, Jin CX, Zhai QG, Chem. Ind. Chem. Eng. Quarterly/CICEQ, 19(3), 359 (2013)

[21] Fernandes DM, Silva N, Pereira C, Moura C, Magalhaes JMCS, Bachiller- Baeza B, Rodr?guez-Ramos I, Guerrero-Ruiz A, Delerue-Matos C, Freire C, Sens. Actuat. B Chem., 218, 128 (2015)

[22] Pinto VC, Sousa PJ, Vieira EMF, Goncalves LM, Minas G, Chem. Eng. J., 404 (2021)

[23] Cai W, Lai T, Du H, Ye J, Sens. Actuat. B Chem., 193, 492 (2014)

[24] Gao L, Yue R, Xu J, Liu Z, Int. J. Electrochem. Sci, 13, 6791 (2018)

[25] Habibi B, Abazari M, Pournaghi-Azar MH, Colloids Surf. B: Biointerfaces, 114, 89 (2014)

[26] Mart?nez-Huitle CA, Fernandes NS, Ferro S, De Battisti A, Quiroz MA, Diam. Relat. Mater., 19(10), 1188 (2010)

[27] Salama NN, Zaazaa HE, Azab SM, Atty SA, El-Kosy NM, Salem MY, Sens. Actuat. B Chem., 240, 1291 (2017)

[28] Durst RA, Pure Appl. Chem., 69(6), 1317 (1997)

[29] Trani A, Petrucci R, Marrosu G, Zane D, Curulli A, J. Electroanal. Chem., 788, 99 (2017)

[30] Yang G, Zhao F, Zeng B, Talanta, 127, 116 (2014)

[31] Choi SH, Kang YC, ChemSusChem, 6(11), 2111 (2013)

[32] Wei X, Chen D, Tang W, Mater. Chem. Phys., 103(1), 54 (2007)

[33] Fu W, Li X, Zhao C, Liu Y, Zhang P, Zhou J, Pan X, Xie E, Mater. Lett., 149, 1 (2015)

[34] Vijayanand S, Joy PA, Potdar HS, Patil D, Patil P, Sens. Actuat. B Chem., 152(1), 121 (2011)

[35] Teow Y, Valiyaveettil S, Nanoscale, 2(12), 2607 (2010)

[36] Zhou T, Sui N, Zhang R, Zhang T, J. Colloid Interface Sci., 537, 520 (2019)

[37] Zhang J, Cheng JP, Li M, Liu L, Liu F, Zhang XB, J. Electroanal. Chem., 743, 38 (2015)

[38] Tian N, Zhou ZY, Sun SG, Cui L, Ren B, Tian ZQ, Chem. Commun., 39, 490 (2006)

[39] G?mez R, P?rez JM, Solla-Gull?n J, Montiel V, Aldaz A, J. Phys. Chem. B, 108(28), 9943 (2004)

[40] Samanta K, Bhattacharya P, Katiyar RS, Iwamoto W, Pagliuso PG, Rettori C, Phys. Rev. B, 73(24) (2006)

[41] Mor?n-L?zaro JP, L?pez-Ur?as F, Mu?oz-Sandoval E, Blanco-Alonso O, Sanchez-Tizapa M, Carreon-Alvarez A, Guill?n-Bonilla H, de la Luz Olvera-Amador M, Guill?n-Bonilla A, Rodr?guez-Betancourtt VM, Nanostruct. Mater. Appl., 701, (2017).

[42] Matin MA, Lee E, Kim H, Yoon WS, Kwon YU, J. Mater. Chem. A, 3(33), 17154 (2015)

[43] Hao S, Zhang B, Ball S, Copley M, Xu Z, Srinivasan M, Zhou K, Mhaisalkar S, Huang Y, J. Power Sources, 294, 112 (2015)

[44] Tajeu KY, Ymele E, Zambou Jiokeng SL, Tonle IK, Electroanalysis (2018).

[45] Zhang L, Wang T, Fan X, Deng D, Li Y, Yan X, Luo L, Int. J. Electrochem. Sci., 16, 4 (2021)

[46] Sawyer DT, Encyclopedia of Physical Science and Technology, Elsevier, 161?197, (2003).

[47] Jesu Amalraj AJ, Umesh NM, Wang SF, J. Mol. Liq., 313, 113554 (2020)

[48] Umesh NM, Wang SF, Rani KK, Pan WC, J. Mater. Sci. Mater. Electron., 31(15), 12973 (2020)

[49] Jesu Amalraj AJ, Narasimha Murthy U, Sea-Fue W, Microchem. J., 169 (2021)

[50] Sun JY, Huang KJ, Wei SY, Wu ZW, Can. J. Chem., 89(6), 697 (2011)

[51] Sun JY, Huang KJ, Wei SY, Wu ZW, Ren FP, Colloids Surf. B Biointerfaces, 84(2), 421 (2011)

[52] Zhao F, Wang F, Zhao W, Zhou J, Liu Y, Zou L, Ye B, Microchim. Acta, 174(3-4), 383 (2011)

[53] Aklilu M, Tessema M, Redi-Abshiro M, Talanta, 76(4), 742 (2008)

[54] Fernandes DM, Silva N, Pereira C, Moura C, Magalhaes JMCS, Bachiller- Baeza B, Rodr?guez-Ramos I, Guerrero-Ruiz A, Delerue-Matos C, Freire C, Sens. Actuat. B Chem., 218, 128 (2015)

[55] Carolina Torres A, Barsan MM, Brett CMA, Food Chem., 149, 215 (2014)