화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.106, 225-232, February, 2022
DOI10.1016/j.jiec.2021.10.032  Export Citation
Efficient solar-light photocatalytic H2 evolution of Mn0.5Cd0.5S coupling with S,N-codoped carbon
Hao Peng1, Congying Huang2, Xiaogang Zheng2, 3, †, and Jing Wen4, †
  • 1College of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing 408100, China
  • 2College of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang, Sichuan 641100, China
  • 3Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808, China
  • 4Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
E-mail:,
The low-cost and highly-efficient photocatalysts for solar-light induced water splitting had drawn great attention to develop the renewable hydrogen economy. To enhance the solar-light driven H2 evolution of Mn0.5Cd0.5S, Mn0.5Cd0.5S was modified by S,N-codoped carbon (3-MCS/SN-C) via the in-situ sulfurization at high temperature. In contrast with Mn0.5Cd0.5S (11.13 mmol g-1 h-1) and S-doped g-C3N4 (0.35 mmol g-1 h-1), the optimal 3-MCS/SN-C with a mass ratio of Mn0.5Cd0.5S to S,N-codoped carbon of 1:3 exhibited the best H2 evolution rate of 27.58 mmol g-1 h-1 and an apparent quantum yield of 27.43% at 400 nm. The photo-corrosion induced to the decreased H2 evolution capacity of 3-MCS/SN-C from 131.13 to 126.52 mmol g-1 after five cycles of 5 h. S,N-codoped carbon could efficiently capture visible light and absorb the photons, leading to the efficient transformation and separation of photogenerated carriers at the junction interface between Mn0.5Cd0.5S and S,N-codoped carbon.
Keywords:Mn0.5Cd0.5S;S,N-codoped carbon;Solar light;H2 evolution
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