화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.106, 297-310, February, 2022
DOI10.1016/j.jiec.2021.11.004  Export Citation
Electronic effects on protective mechanism of electropolymerized coatings based on N-substituted aniline derivatives for mild steel in saline solution
Hao Liu, Baomin Fan†, Zining Liu, Xiaoqi Zhao, Biao Yang, Xingwen Zheng1, and Hua Hao2
  • College of Chemistry and Materials Engineering, Beijing Technology and Business University, Beijing 100048, China
  • 1Key Laboratory of Material Corrosion and Protection of Sichuan Province, Sichuan University of Science & Engineering, Zigong 643000, China
  • 2Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail:
Polyaniline (PANI), poly(N-methylaniline) (PNMA) and poly(N-formylanilide) (PNFA) coatings were fabricated over mild steel via chronoamperometric strategy in oxalate electrolyte. Scanning electron microscope (SEM), attenuated total reflection infrared spectroscopy (ATR-IR) and X-ray photoelectron spectroscopy (XPS) evidenced the polymerization of monomers. Anticorrosive effects of PANI, PNMA and PNFA coatings for steel substrate were evaluated during long-term immersion in 3.5% NaCl solution by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and frequency modulation (EFM). Morphological variation for coated specimens before and after immersion in NaCl solution was also monitored by SEM and atomic force microscope (AFM). Differentiated protection capability were observed for three coatings following the sequence of PNFA > PNMA > PANI. Through electrochemical and interfacial analyses, electroactivity and physical barrier were ascertained as the critical factors, especially the former one, in the long-term protection capacity. Electroactivity was distinguished by the elevated apparent current density from non-destructive EFM measurements. Furthermore, electron-donation and -withdrawal effects of N-substituents played an essential role in coating electroactivity. In detail, N-substituents improved the anodic protection and physical barrier of PNMA and PNFA coatings. Particularly, formyl with electron-withdrawal effect reinforced the anodic protection and thus the superior the anticorrosion efficiency of PNFA for underlying steel.
Keywords:Aniline derivatives;Electropolymerization;Coating;Anodic protection;Mild steel;Electrochemical frequency modulation
  1. M.A. Quraishi, D.S. Chauhan, F.A. Ansari, J. Mol. Liq., 329 (2021)
  2. Machmudah S, Zulhijah R, Wahyudiono, Setyawan H, Goto H, Kanda M, Chem. Eng. J., 268, 76 (2015)
  3. Wen JX, Lei JL, Chen JL, Gou J, Li YJ, Li L, Chem. Eng. J., 392 (2020)
  4. Huang XL, Yu L, Dong YS, Corros. Sci., 182 (2021)
  5. Umoren SA, Solomon MM, Prog. Mater. Sci., 104, 380 (2019)
  6. Fan GF, Liu H, Fan BM, Ma YC, Hao H, Yang B, J. Mol. Liq., 311 (2020)
  7. D.L. Wang, Y.M. Li, B. Chen, L. Zhang, Chem. Eng. J., 402 (2020)
  8. Zadeh MK, Yeganeh M, Shoushtari MT, Esmaeilkhanian A, Synthetic Met., 274 (2021)
  9. Diaz AF, Kanazawa KK, Gardini GP, J. Chem. Soc. Chem. Commun., 14, 635 (2021)
  10. Liu H, Fan BM, Fan GF, Ma YC, Hao H, Zhang W, J. Mater. Sci. Technol., 72, 202 (2021)
  11. Gupta DK, Neupane S, Singh S, Karki N, Yadav AP, Prog. Org. Coat., 152 (2021)
  12. Chen ZH, Zhang GH, Yang WZ, Xu B, Chen Y, Yin XS, Liu Y, Chem. Eng. J., 393 (2020)
  13. Garcia-Cabezon C, Garcia-Hernandez C, Rodriguez-Mendez ML, Martin- Pedrosa F, J. Mater. Sci. Technol., 37, 85 (2020)
  14. Ashassi-Sorkhabi H, Kazempour A, J. Mol. Liq., 309 (2020)
  15. Gao FJ, Mu J, Bi ZX, Wang S, Li ZL, Prog. Org. Coat., 151 (2021)
  16. Lu Y, Wang S, Xiong CX, Hu GH, Synthetic Met., 270 (2020)
  17. Yagan A, Int. J. Electrochem. Sci., 14, 2906 (2019)
  18. Zeybek B, Aksun E, Prog. Org. Coat., 81, 1 (2015)
  19. Wan S, Miao CH, Wang RM, Zhang ZF, Dong ZH, Prog. Org. Coat., 129, 187 (2019)
  20. Liu H, Fan BM, Fan GF, Zhao XQ, Liu ZN, Hao H, Yang B, J. Alloy. Compd., 872 (2021)
  21. Ma YC, Fan BM, Liu H, Fan GF, Hao H, Yang B, Appl. Surf. Sci., 514 (2020)
  22. Bucha��a T, Chudoba A, Roszak S, Struct. Chem., 27, 185 (2015)
  23. Bonechi B, Innocenti M, Vanossi D, Fontanesi C, J. Phys. Chem. A, 125, 34 (2021)
  24. Luo ZQ, Ma Y, He H, Mu WH, Zhou XT, Liao WY, Ma HY, J. Am. Ceram. Soc., 104, 1120 (2020)
  25. Kumar AM, Gasem ZM, Prog. Org. Coat., 78, 387 (2015)
  26. Bahramian A, Eyraud M, Maria S, Vacandio F, Djenizian T, Knauth P, Corros. Sci., 149, 75 (2019)
  27. M.C.G. Sabor?o, S. Lanzalaco, G. Fabregat, J. Puiggal?, F. Estrany, C. Alem?n, J. Phys. Chem. C, 122, 1078 (2018)
  28. Mrad M, Amor YB, Dhouibi L, Montemor F, Synthetic Met, 234, 145 (2017)
  29. Wang MX, Yun H, Tan KQ, Guo AQ, Ling JW, Jiang FF, Shen XX, Xu QJ, Prog. Org. Coat., 149 (2020)
  30. Wang YL, Zhang SH, Wang P, Chen SB, Lu ZX, Li WH, J. Taiwan Inst. Chem. E, 103, 190 (2019)
  31. Chen ZH, Yang WZ, Yin XS, Chen Y, Liu Y, Xu B, Prog. Org. Coat., 146 (2020)
  32. Fan BM, Hao H, Yang B, Li Y, Res. Chem. Intermed., 44, 5711 (2018)
  33. Shi SG, Zhao YY, Zhang ZM, Yu LM, Prog. Org. Coat., 132, 227 (2019)
  34. Al-Saadi S, Raman RKS, Anisur MR, Ahmed S, Crosswell J, Alnuwaiser M, Panter C, Corros. Sci., 182 (2021)
  35. Liu S, Pan TJ, Wang RF, Yue Y, Shen J, Prog. Org. Coat., 136 (2019)
  36. Ma YC, Fan BM, Zhou TT, Hao H, Yang B, Sun H, Polymers, 11, 635 (2019)
  37. D.K. Kozlica, A. Kokalj, I. Milo?ev, Corros. Sci., 182 (2021)
  38. Wysocka J, Cieslik M, Krakowiak S, Ryl J, Electrochim. Acta, 289, 175 (2018)
  39. Viltres H, Odio OF, Biesinger MC, Montiel G, Borja R, Reguera E, ChemistrySelect, 5, 4875 (2020)
  40. Wang SC, Liu FW, Gao CM, Wan T, Wang LH, Wang L, Wang L, Chem. Eng. J., 370, 322 (2019)
  41. He YP, Wang X, Huang H, Zhang PP, Chen BM, Guo ZC, Appl. Surf. Sci., 469, 446 (2019)
  42. Fan BM, Ma YC, Wang MM, Hao H, Yang B, Lv JY, Sun H, J. Mol. Liq., 292 (2019)
  43. Li XP, Li JL, Kang FY, Ionics, 25, 1045 (2019)
  44. Ma YC, Fan BM, Hao H, Lv JY, Feng YH, Yang B, Chem. J. Chinese U., 40, 96 (2019)
  45. Wang MM, Fan BM, Wen BY, Jiang C, Sci. China Technol. Sc., 63, 2098 (2020)
  46. Fin?gar M, Corros. Sci., 182 (2021)
  47. Bahremand F, Shahrabi T, Ramezanzadeh B, J. Hazard. Mater., 403 (2021)