Template and binder free 1D cobalt nickel hydrogen phosphate electrode materials for supercapacitor application

Jae Yeong Heo; Rajangam Vinodh; Hee-Je Kim; Rajendran Suresh Babu; Kungumaraj Krishna Kumar; Chandu V.V. Muralee Gopi; Sungshin Kim

Journal of Industrial and Engineering Chemistry, Vol.106, 328-339, February, 2022

DOI10.1016/j.jiec.2021.11.010 Export Citation

Template and binder free 1D cobalt nickel hydrogen phosphate electrode materials for supercapacitor application

Jae Yeong Heo, Rajangam Vinodh^{1, †}, Hee-Je Kim, Rajendran Suresh Babu², Kungumaraj Krishna Kumar³, Chandu V.V. Muralee Gopi⁴, and Sungshin Kim^†

School of Electrical and Computer Engineering, Pusan National University, Busan 46241, Republic of Korea
¹Department of Electronics Engineering, Pusan National University, Busan 46241, Republic of Korea
²Laboratory of Experimental and Applied Physics, Centro Federal de Educação Tecnológica Celso Suckow da Fonseca, Av. Maracanã Campus 229, Rio de Janeiro 20271-110, Brazil
³Central Instrumentation Laboratory, Vels Institute of Science Technology and Advanced Studies, Tamil Nadu, Chennai 600 117, India
⁴Department of Electrical Engineering, University of Sharjah, Sharjah, P.O. Box 27272, UAE, United Arab Emirates

E-mail:,

Herein, we synthesized 1D bimetallic hydrogen phosphate [CoxNix(HPO4)] nanorods by using a simple and effective chemical bath deposition method for supercapacitor applications. The prepared CoxNix(HPO4) was analyzed by Fourier transform infrared (FT-IR) spectroscopy and X-ray diffraction (XRD) pattern. The surface morphology was envisaged by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) methods. The porous nature and surface area of the materials were characterized by nitrogen sorption isotherm and a high specific surface area of 153 m2 g-1 was found to be for Co0.75Ni0.25(HPO4). The Co0.75Ni0.25(HPO4) displays a maximum specific capacity of 475 mA h g-1 at 1 A g-1 in a three-electrode configuration using 3 M KOH as the electrolyte. Co0.75Ni0.25(HPO4) exhibits almost 94.8% of its initial specific capacity over 5000 GCD cycles at 10 A g-1. Furthermore, the fabricated asymmetric supercapacitor (ASC) with Co0.75Ni0.25(HPO4) and activated carbon (AC) showed a high specific capacitance of 182.5F g-1 at 0.5 A g-1. The ASC device delivered a maximum energy density of 64.88 Wh kg-1 at a power density of 800 W kg-1.

Keywords:Bimetallic hydrogen phosphate;Specific capacity;Capacity retention;Surface area;Energy storage

[References]

Zhong YU, Liu T, Zhang A, Cui L, Liu X, Zheng R, Liu R, J. Alloys Compd., 850 (2021)
Atchudan R, Edison TNJI, Shanmugam M, Perumal S, Vinodh R, Somanathan T, Lee YR, J. Ind. Eng. Chem., 98, 308 (2021)
Kim I, Vinodh R, Gopi CVVM, Kim HJ, Babu RS, Deviprasath C, Devendiran M, Kim S, J. Energy Storage, 43 (2021)
Vinodh R, Sasikumar Y, Kim HJ, Atchudan R, Yi M, J. Ind. Eng. Chem., 104, 155 (2021)
Vivekanandan R, Mohan NV, Balamuralitharan B, Rajmohan R, Vinodh R, Aravindharaja S, Kim HJ, Ionics, 26, 345 (2020)
Vidhya MS, Ravi G, Yuvakumar R, Velauthapillai D, Thambidurai M, Dang C, Saravanakumar B, RSC Adv., 10, 19410 (2020)
Jing C, Huang Y, Xia L, Chen Y, Wang X, Liu X, Dong B, Dong F, Li S, Zhang Y, Appl. Surf. Sci., 496 (2019)
Ramesh S, Lee YJ, Shin K, Sanjeeb L, Karuppasamy K, Vikraman D, Kathalingam A, Kim HS, Kim HS, Kim JH, Int. J. Energy Res., 45, 19547 (2021)
Gopi CVVM, Sambasivam S, Raghavendra KVG, Vinodh R, Obaidat IM, Kim HJ, J. Energy Storage, 30 (2020)
Anitha T, Reddy AE, Vinodh R, Kim HJ, Cho YR, J. Energy Storage, 30 (2020)
Wang H, Gao Q, Hu J, J. Power Sources, 195, 3017 (2010)
Yuan C, Li J, Hou L, Zhang X, Shen L, Lou XW, Adv. Funct. Mater., 22, 4592 (2012)
Xia X, Chao D, Fan Z, Guan C, Cao X, Zhang H, H.J. Fan, ACS Nano, 6, 5531 (2012)
Pang H, Wang S, Shao W, Zhao S, Yan B, Li X, Li S, Chen J, Du W, Nanoscale, 5, 5752 (2013)
Mirghni AA, Oyedotun KO, Olaniyan O, Mahmoud BA, Manyala NFSN, RSC Adv., 9, 25012 (2019)
Zhao Y, Chen Z, Xiong DB, Qiao Y, Tang Y, Gao F, Sci Rep., 6, 17613 (2016)
Gopi CVVM, Rana PJS, Padma R, Vinodh F, Kim HJ, J. Mater. Chem. A, 7, 6374 (2019)
Gopi CVVM, Vinodh R, Sambasivam S, Obaidat IM, Singh S, Kim HJ, Chem. Eng. J., 381 (2020)
Nam HW, Gopi CVVM, Sambasivam S, Vinodh R, Raghavendra KVG, Kim HJ, Obaidat IM, Kim S, J. Energy Storage, 27 (2020)
Zhang Y, Shi J, Hu Y, Huang Z, Guo L, Catal. Sci. Technol., 6, 8080 (2016)
Yu XN, Qian CX, Wang X, J. Chil. Chem. Soc., 60, 2885 (2015)
Wang J, Zeng HC, ACS Appl. Mater. Interfaces, 10, 6288 (2018)
Wang D, Wang Y, Fu Z, Xu Y, Yang LX, Wang F, Guo X, Sun W, Yang ZL, A.C.S. Appl, Mater. Interfaces, 13, 34507 (2021)
Chen C, Zhang N, He Y, Liang B, Ma R, Liu X, A.C.S. Appl, Mater. Interfaces, 8, 23114 (2016)
Guan X, Huang M, Yang L, Wang G, Guan X, Chem. Eng. J., 372, 151 (2019)
Pan Y, Sun K, Lin Y, Cao X, Cheng Y, Liu S, Zeng L, Cheong WC, Zhao D, Wu K, Liu Z, Liu Y, Wang D, Peng Q, Chen C, Li Y, Nano Energy, 56, 411 (2019)
Yang J, Yu C, Fan X, Liang S, Li S, Huang H, Ling Z, Hao C, Qiu J, Energy Environ. Sci., 9, 1299 (2016)
Li C, Balamurugan J, Kim NH, Lee JH, Adv. Energy Mater., 8, 1702014 (2018)
Tao K, Gong Y, Lin J, Nano Energy, 55, 65 (2019)
Xing T, Ouyang Y, Chen Y, Zheng L, Wu C, Wang X, J. Energy Storage, 28 (2020)
El-Deen AG, El-Shafei MH, Hessein A, Hassanin AH, Shaalan NM, El-Moneim AA, Nanotechnology, 31 (2020)
Masikhwa TM, Barzegar F, Dangbegnon JK, Bello A, Madito MJ, Momodu D, Manyala N, RSC Adv., 6, 38990 (2016)
Zhang J, Feng H, Yang J, Qin Q, Fan H, Wei C, Zheng W, ACS Appl. Mater. Interfaces, 7, 21735 (2015)
Li J, Zou PC, Yao WT, Liu P, Kang FY, Yang C, New Carbon Mater., 35, 112 (2020)
Neeraj NS, Mordina B, Srivastava AK, Mukhopadhyay K, Prasad NE, Appl. Surf. Sci., 2019, 473 (2019)

[1] Zhong YU, Liu T, Zhang A, Cui L, Liu X, Zheng R, Liu R, J. Alloys Compd., 850 (2021)

[2] Atchudan R, Edison TNJI, Shanmugam M, Perumal S, Vinodh R, Somanathan T, Lee YR, J. Ind. Eng. Chem., 98, 308 (2021)

[3] Kim I, Vinodh R, Gopi CVVM, Kim HJ, Babu RS, Deviprasath C, Devendiran M, Kim S, J. Energy Storage, 43 (2021)

[4] Vinodh R, Sasikumar Y, Kim HJ, Atchudan R, Yi M, J. Ind. Eng. Chem., 104, 155 (2021)

[5] Vivekanandan R, Mohan NV, Balamuralitharan B, Rajmohan R, Vinodh R, Aravindharaja S, Kim HJ, Ionics, 26, 345 (2020)

[6] Vidhya MS, Ravi G, Yuvakumar R, Velauthapillai D, Thambidurai M, Dang C, Saravanakumar B, RSC Adv., 10, 19410 (2020)

[7] Jing C, Huang Y, Xia L, Chen Y, Wang X, Liu X, Dong B, Dong F, Li S, Zhang Y, Appl. Surf. Sci., 496 (2019)

[8] Ramesh S, Lee YJ, Shin K, Sanjeeb L, Karuppasamy K, Vikraman D, Kathalingam A, Kim HS, Kim HS, Kim JH, Int. J. Energy Res., 45, 19547 (2021)

[9] Gopi CVVM, Sambasivam S, Raghavendra KVG, Vinodh R, Obaidat IM, Kim HJ, J. Energy Storage, 30 (2020)

[10] Anitha T, Reddy AE, Vinodh R, Kim HJ, Cho YR, J. Energy Storage, 30 (2020)

[11] Wang H, Gao Q, Hu J, J. Power Sources, 195, 3017 (2010)

[12] Yuan C, Li J, Hou L, Zhang X, Shen L, Lou XW, Adv. Funct. Mater., 22, 4592 (2012)

[13] Xia X, Chao D, Fan Z, Guan C, Cao X, Zhang H, H.J. Fan, ACS Nano, 6, 5531 (2012)

[14] Pang H, Wang S, Shao W, Zhao S, Yan B, Li X, Li S, Chen J, Du W, Nanoscale, 5, 5752 (2013)

[15] Mirghni AA, Oyedotun KO, Olaniyan O, Mahmoud BA, Manyala NFSN, RSC Adv., 9, 25012 (2019)

[16] Zhao Y, Chen Z, Xiong DB, Qiao Y, Tang Y, Gao F, Sci Rep., 6, 17613 (2016)

[17] Gopi CVVM, Rana PJS, Padma R, Vinodh F, Kim HJ, J. Mater. Chem. A, 7, 6374 (2019)

[18] Gopi CVVM, Vinodh R, Sambasivam S, Obaidat IM, Singh S, Kim HJ, Chem. Eng. J., 381 (2020)

[19] Nam HW, Gopi CVVM, Sambasivam S, Vinodh R, Raghavendra KVG, Kim HJ, Obaidat IM, Kim S, J. Energy Storage, 27 (2020)

[20] Zhang Y, Shi J, Hu Y, Huang Z, Guo L, Catal. Sci. Technol., 6, 8080 (2016)

[21] Yu XN, Qian CX, Wang X, J. Chil. Chem. Soc., 60, 2885 (2015)

[22] Wang J, Zeng HC, ACS Appl. Mater. Interfaces, 10, 6288 (2018)

[23] Wang D, Wang Y, Fu Z, Xu Y, Yang LX, Wang F, Guo X, Sun W, Yang ZL, A.C.S. Appl, Mater. Interfaces, 13, 34507 (2021)

[24] Chen C, Zhang N, He Y, Liang B, Ma R, Liu X, A.C.S. Appl, Mater. Interfaces, 8, 23114 (2016)

[25] Guan X, Huang M, Yang L, Wang G, Guan X, Chem. Eng. J., 372, 151 (2019)

[26] Pan Y, Sun K, Lin Y, Cao X, Cheng Y, Liu S, Zeng L, Cheong WC, Zhao D, Wu K, Liu Z, Liu Y, Wang D, Peng Q, Chen C, Li Y, Nano Energy, 56, 411 (2019)

[27] Yang J, Yu C, Fan X, Liang S, Li S, Huang H, Ling Z, Hao C, Qiu J, Energy Environ. Sci., 9, 1299 (2016)

[28] Li C, Balamurugan J, Kim NH, Lee JH, Adv. Energy Mater., 8, 1702014 (2018)

[29] Tao K, Gong Y, Lin J, Nano Energy, 55, 65 (2019)

[30] Xing T, Ouyang Y, Chen Y, Zheng L, Wu C, Wang X, J. Energy Storage, 28 (2020)

[31] El-Deen AG, El-Shafei MH, Hessein A, Hassanin AH, Shaalan NM, El-Moneim AA, Nanotechnology, 31 (2020)

[32] Masikhwa TM, Barzegar F, Dangbegnon JK, Bello A, Madito MJ, Momodu D, Manyala N, RSC Adv., 6, 38990 (2016)

[33] Zhang J, Feng H, Yang J, Qin Q, Fan H, Wei C, Zheng W, ACS Appl. Mater. Interfaces, 7, 21735 (2015)

[34] Li J, Zou PC, Yao WT, Liu P, Kang FY, Yang C, New Carbon Mater., 35, 112 (2020)

[35] Neeraj NS, Mordina B, Srivastava AK, Mukhopadhyay K, Prasad NE, Appl. Surf. Sci., 2019, 473 (2019)