A novel covalent organic framework with multiple adsorption sites for removal of Hg2+ and sensitive detection of nitrofural

Linyu Wang; Yonghai Song; Ying Luo; Li Wang

Journal of Industrial and Engineering Chemistry, Vol.106, 374-381, February, 2022

DOI10.1016/j.jiec.2021.11.014 Export Citation

A novel covalent organic framework with multiple adsorption sites for removal of Hg2+ and sensitive detection of nitrofural

Linyu Wang, Yonghai Song, Ying Luo, and Li Wang^†

Key Laboratory of Functional Small Organic Molecule, Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

E-mail:

It is urgent to control serious drug pollution and heavy metal ion pollution. Covalent organic framework (COF) is becoming a promising material for the removal of heavy metal ion and adsorption of organic small molecule because of the designed functional sites, ordered pore channel, high specific surface area and abundant π electrons. Herein, 2,4,6-triformylphloroglucinol (TFP) and benzene-1,3,5- tricarbohydrazide (BTH) was used to design a stable yet efficient beta-ketoenamine COF (COFTFP-BTH) adsorbent, which would provide multiple adsorption sites of Hg2+ by dense acylhydrazine. The maximum adsorption capacity of COFTFP-BTH toward Hg2+ achieved 909 mg g-1, coinciding with Langmuir adsorption and pseudo-second-order adsorption kinetic model, with the h value as high as 71.43 mg g-1 min-1. COFTFP-BTH was also grown on NH2-carbon nanotubes (CNT) to form a novel COFTFP-BTH@NH2-CNT composite for sensitive detection of nitrofural (NF). The NF sensor based on COFTFP-BTH@NH2-CNT showed a low detection limit (3.2 nM) and a wide linear range (9.6 nM-100 μM). The excellent performances were also attributed to the ordered channels of COFTFP-BTH exposing more adsorption sites of Hg2+ and NF, as well as the good stability of beta-ketoenamine COFTFP-BTH.

Keywords:Covalent organic frameworks;Electrochemical sensor;NH2-CNT;Nitrofural;Adsorption;Hg2+

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[2] Yao BJ, Wu WX, Ding LG, Dong YB, J. Org. Chem., 86, 3024 (2021)

[3] Wang JC, Kan X, Shang JY, Qiao H, Dong YB, J. Am. Chem. Soc., 142, 16915 (2020)

[4] Zhang C, Cui M, Ren J, Xing Y, Li N, Zhao H, Liu P, Ji X, Li M, Chem. Eng. J., 401 (2020)

[5] Ko WC, Kim M, Kwon YJ, J. Mater. Chem. A, 8, 19246 (2020)

[6] Zhang S, Yang Q, Xu X, Liu X, Li Q, Guo J, Torad NL, Alshehri SM, Ahamad T, Hossain MSA, Kaneti YV, Yamauchi Y, Nanoscale, 12, 15611 (2020)

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[8] Ghosh S, Nakada A, Springer MA, Kawaguchi T, Suzuki K, Kaji H, Baburin I, Kuc A, Heine T, Suzuki H, Abe R, Seki S, J. Am. Chem. Soc., 142, 9752 (2020)

[9] Sun D, Kim DP, ACS Appl. Mater. Interfaces, 12, 20589 (2020)

[10] Yan T, Lan Y, Tong M, Zhong C, ACS Sustainable Chem. Eng., 7, 1220 (2018)

[11] Altundal OF, Altintas C, Keskin S, J. Mater. Chem. A, 8, 14609 (2020)

[12] Liu X, Lim GJH, Wang Y, Zhang L, Mullangi D, Wu Y, Zhao D, Ding J, Cheetham AK, Wang J, Chem. Eng. J., 403 (2021)

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[16] Ding SY, Dong M, Wang YW, Chen YT, Wang HZ, Su CY, Wang W, J. Am. Chem. Soc., 138, 3031 (2016)

[17] Huang N, Zhai L, Xu H, Jiang D, J. Am. Chem. Soc., 139, 2428 (2017)

[18] Cui WR, Jiang W, Zhang CR, Liang RP, Liu J, Qiu JD, ACS Sustainable Chem. Eng., 8, 445 (2019)

[19] Li Y, Yang C, Yan X, Chem. Commun., 53, 2511 (2017)

[20] Zhuang S, Liu Y, Wang J, J. Hazard. Mater., 383 (2020)

[21] Abdelrahman EA, El-Reash YGA, Youssef HM, Kotp YH, Hegazey RM, J. Hazard. Mater., 401 (2021)

[22] Wu J, Wang T, Wang J, Zhang Y, Pan WP, Sci. Total Environ., 754 (2021)

[23] Zhao Y, Xia K, Zhang Z, Zhu Z, Guo Y, Qu Z, Nanomater, 9, 455 (2019)

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[25] Li X, Ma W, Li H, Zhang Q, Liu H, Coord. Chem. Rev., 408 (2020)

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[31] Xu L, Wang F, Ge X, Liu R, Xu M, Yang J, Microporous Mesoporous Mater., 287, 65 (2019)

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[36] Wang L, Yang Y, Liang H, Wu N, Peng X, Wang L, Song Y, J. Hazard. Mater., 409 (2021)

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[46] Rajakumaran R, Sukanya R, Chen SM, Karthik R, Breslin CB, Shafi PM, Inorg. Chem., 60, 2464 (2021)

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[49] Wang L, Xu M, Xie Y, Qian C, Ma W, Wang L, Song Y, Sens. Actuators, B, 285, 264 (2019)

[50] Hu X, Liu Y, Xia Y, Zhao F, Zeng B, Food Chem., 363 (2021)

[51] Song Y, Xu M, Gong C, Shen Y, Wang L, Xie Y, Wang L, Sens. Actuators, B, 257, 792 (2018)

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