화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.106, 520-536, February, 2022
DOI10.1016/j.jiec.2021.11.029  Export Citation
Electrochemical Ce(III)/Ce(IV) interconversion, electrodeposition, and catalytic CO ↔ CO2 interconversion over terpyridine-modified indium tin oxide electrodes
So Jeong Park1, Ju Young Maeng1, Min Hee Joo1, 2, Jun-Gill Kang1, 3, Choong Kyun Rhee1, and Youngku Sohn1, 2, †
  • 1Department of Chemistry, Chungnam National University, Daejeon 34134, Republic of Korea
  • 2Department of Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon 34134, Republic of Korea
  • 3IDK, #306 IT Venture Town, Techno 9-Ro, Yuseong, Daejeon 34839, Republic of Korea
E-mail:
Indium tin oxide (ITO) has extensively used as an electrode in diverse application areas of electrochemistry, displays, photovoltaics, and catalysts. Herein, terpyridine-modified ITO and thioterpyridinefunctionalized Au-modified ITO electrodes were prepared and evaluated for electrochemical redox behaviors and conversion rates of Ce(III)/Ce(IV) ions, and recycling recovery rates on the newly developed electrode by cyclic voltammetry and amperometry. Scanning electron microscopy, X-ray photoelectron spectroscopy, Ultraviolet photoelectron spectroscopy, X-ray diffraction crystallography, and fluorescence spectroscopy were employed for the physiochemical properties of the demonstrated electrodes before and after electrochemistry. The interfacial energy level was examined by ultraviolet photoelectron spectroscopy for ITO-Au and ITO-Au-STpy. Density functional theory calculations were performed to examine complexation between the functionalized ligand and Ce(III)/Ce(IV) ions by obtaining molecular orbital energy levels and thermodynamics. Thermal CO oxidation catalytic activity was tested for Ceelectrodeposited ITO electrode. In addition, electrochemical CO2 reduction performance was evaluated for Au-modified ITO electrode with and without thioterpyridine-functionalization.
Keywords:Ce(III,IV) ion;Terpyridine-functionalization;Electrodeposition;Density functional theory;Interfacial energy level;CO/CO2 catalytic interconversion
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