화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.107, 100-108, March, 2022
DOI10.1016/j.jiec.2021.11.033  Export Citation
Scandium-doped barium ceria ferrites-based composite mixed conducting hollow fiber membranes for H2 and O2 permeation
Jian Song1, 2, Claudia Li3, Shao Zhang2, Kai Wang4, Bo Meng1, 5, Xiaoyao Tan2, †, Jaka Sunarso3, †, and Shaomin Liu6
  • 1Department of Chemical Engineering, Shandong University of Technology, Zibo 255049, PR China
  • 2State Key Laboratory of Separation Membranes and Membrane Processes, Department of Chemical Engineering, Tiangong University, Tianjin 300387, PR China
  • 3Research Centre for Sustainable Technologies, Faculty of Engineering, Computing and Science, Swinburne University of Technology, Jalan Simpang Tiga, 93350 Kuching Sarawak, Malaysia
  • 4WA School of Mines: Minerals Energy and Chemical Engineering, Curtin University, Perth, Western Australia 6102, Australia, Austria
  • 5, China
  • 6College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, PR China
E-mail:,
BaCeO3-based ceramics are a unique class of perovskites that exhibit protonic and oxygen ionic conduction, which are ideal for high temperature hydrogen separation applications. This work features Sc-doped BCFe composites with nominal composition of BaCe0.70Fe0.30-xScxO3−δ (BCFSc) (x = 0, 0.05, 0.1, 0.15, and 0.2) that exhibit enhanced thermal, chemical, and mechanical stability. The BCFSc20 (x = 0.20) hollow fiber membranes demonstrated the highest hydrogen and oxygen fluxes among the Sc-doped composites of up to 0.32 and 0.20 mL min−1 cm−2, respectively, at 1000 °C. The BCFSc20 hollow fibers also displayed excellent stability under the hydrogen and oxygen permeation environments, while the permeation performance of the other BCFSc samples with low Sc content gradually deteriorated over the 120-h stability test.
Keywords:Hollow fiber membrane;Hydrogen permeation;Oxygen permeation;Phase inversion;Scandium doping
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