화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.107, 239-248, March, 2022
DOI10.1016/j.jiec.2021.11.051  Export Citation
Large-scale synthesis of functional tungsten oxide with controlled oxygen-deficiency by a continuous screw reactor
Eri Kumai, Fuyumi Shimono, Manabu Tanaka, Takayuki Watanabe†, Takeshi Hoshino1, Satoshi Hosoda1, Hiroshi Kanamori1, and Yuji Fujita2
  • Department of Chemical Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan
  • 1Japan Aerospace Exploration Agency (JAXA), 3-1-1 Yoshinodi, Chuo-ku, Sagamihara, Kanagawa 252-5210, Japan
  • 2Nano-Science Laboratory Corporation, 1-7-701 Matsugasaki-kumojicho, Sakyo-ku, Kyoto-shi, Kyoto 606-8104, Japan
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Oxygen-deficient tungsten oxide is one of the promising materials for broad applications due to its enhanced characteristics owing to the oxygen-deficiency. Development of a mass production process is crucial in consideration of the increasing demand of this material in industrial purposes. A continuous screw reactor was employed to the production of oxygen-deficient tungsten oxide. The effects of hydrogen concentration and the reduction time on the composition of products were investigated. The maximum WO2.72 mole fraction of 0.95 was achieved by optimum hydrogen concentration and reduction time. X-ray Photoelectron Spectroscopy (XPS) spectra of the products indicated the introduction of oxygen-deficiency. Anisotropic crystal growth in the (010) direction is found in the cross-section observation by Scanning Electron Microscope (SEM). The displacing value from High-Resolution Transmission Electron Microscope (HR-TEM) demonstrated the existence of WO2.72. The reaction kinetic was investigated by thermogravimetric analysis. Estimated activation energy supported the results from the continuous process. This work suggests the promising process for the large-scale production of functional materials.
Keywords:Oxygen-deficient metal oxides;Large-scale synthesis;Continuous screw reactor;Hydrogen reduction;WO3
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