화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.107, 320-332, March, 2022
DOI10.1016/j.jiec.2021.12.001  Export Citation
Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation
David Skoda1, †, Barbora Hanulikova1, Ales Styskalik2, Vit Vykoukal2, 3, Petr Machac2, Pavel Urbanek1, Eva Domincova Bergerova1, Lucie Simonikova2, and Ivo Kuritka1
  • 1Centre of Polymer Systems, Tomas Bata University in Zlin, tr. Tomase Bati 5678, Zlin, CZ 76001, Czech Republic
  • 2Department of Chemistry, Faculty of Science, Masaryk University, Kotlarska 2, Brno, CZ 61137, Czech Republic
  • 3Central European Institute of Technology, Masaryk University, Kamenice 5, Brno, CZ 62500, Czech Republic
E-mail:
In this work, a novel synthesis of homogeneous molybdenum silicate spheres under non-aqueous conditions is presented. A preparation method is based on the condensation of molybdenum metal–organic framework-based precursor solution prepared via a microwave-assisted approach from bis(acetylacetonato)dioxomolybdenum and biphenyl-4,4′-dicarboxylic acid with 3-aminopropyltriethoxysilane under non-aqueous conditions. The as-prepared product was calcined at 500 °C to obtain amorphous and porous molybdenum silicate microspheres with homogeneously distributed molybdenum species within silicate matrix. The microspheres exhibit an average size of about 480 nm. This material was further studied as a heterogeneous catalyst for the epoxidation of olefins via the model catalytic epoxidation of cyclohexene with cumylhydroperoxide. High catalytic activity at the moderate temperature (65 °C) with the conversion of 86% after 2 h and the high selectivity to cyclohexene oxide has been achieved. In addition, molybdenum silicate microspheres exhibit catalytic activity and high selectivity in the oxidation of aniline to nitrosobenzene.
Keywords:Molybdenum silicate;Non-aqueous;Microspheres;Catalyst;Epoxidation;Aniline oxidation
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