화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.109, 147-154, May, 2022
DOI10.1016/j.jiec.2022.01.034  Export Citation
Ultra-sensitive, selective and rapid carcinogenic Bisphenol A contaminant determination using low-dimensional facile binary Mg-SnO2 doped microcube by potential electro-analytical technique for the safety of environment
Mohammed M. Rahman1, 2, †, Jahir Ahmed3, Abdullah M. Asiri1, 2, and Sulaiman Y. Alfaifi1, 4
  • 1Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
  • 2Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
  • 3Promising Centre for Sensors and Electronic Devices (PCSED), Advanced Materials and Nano-Research Centre, Najran University, P.O. Box: 1988, Najran 11001, Saudi Arabia
  • 4, Saudi Arabia
E-mail:
Herein, a novel composite material (Magnesium co-doped Tin (IV) oxide; MTO) microcube was synthesized by a simple solution method in basic phase and successfully characterized. It has been used the Fourier Transform Infrared Spectroscopy (FTIR), X-ray Photoelectron Spectroscopy (XPS), X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM), and Energy-Dispersive Spectroscopy (EDS) techniques for the characterization of MTO. The MTO microcube was used later to modify gold-coated μ-chips to detect unsafe toxin, bisphenol A (BPA) in aqueous medium. Notable sensing performance was achieved with excellent sensitivity (1.63 μAμM-1cm-2), fast response time (~11 s), wide linear dynamic range (LDR = 0.10 nM – 1.0 mM: R2 = 0.9997), ultra-low detection limit (2.7 ± 0.1 pM at S/N = 3) and excellent reproducibility and repeatability for the MTO/Au/l-Chip sensor. This MTO fabricated gold-coated l-chip was further applied with appropriate quantification and determination results in real environmental sample analyses.
Keywords:Bisphenol A detection;MTO microcube;Tiny micro-Chip;Real sample analysis;Electrochemical method
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