화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.109, 155-160, May, 2022
DOI10.1016/j.jiec.2022.01.039  Export Citation
Synthesis of surface-tuned polyacrylonitrile particles and its application to CO2 separation
Tae-Gyun Kwon1, Beom Jun Kim2, Oong Hyeon Jo3, Beom-Goo Kang3, †, and Sang Wook Kang2, 4, †
  • 1Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
  • 2Department of Chemistry, Sangmyung University, Seoul 03016, Republic of Korea
  • 3Department of Chemical Engineering, Soongsil University, Seoul 06978, Republic of Korea
  • 4Department of Chemistry and Energy Engineering, Sangmyung University, Seoul 03016, Republic of Korea
E-mail:,
We synthesized the surface-tuned polyacrylonitrile (PAN) colloid particles as sulfate ions with a size of 75.6 nm. The synthesized PAN particles were introduced into a polymeric membrane for CO2/N2 separation. Poly(ethylene oxide) (PEO) was used as the polymer matrix. The PEO/PAN colloid composite membranes showed an improved ideal CO2 selectivity of 23, whereas the PEO membrane showed a selectivity of 6.7. This improved separation performance is attributable to the difference in solubilities of CO2 and N2 due to the presence of polar groups on the colloid surfaces, resulting in the enhanced separation performance.
Keywords:CO2;Membrane;Polyacrylonitirile;Facilitated transport;Separation
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