화학공학소재연구정보센터
Journal of Vacuum Science & Technology A, Vol.17, No.5, 2612-2618, 1999
Silicon nitride films deposited at substrate temperatures < 100 degrees C in a permanent magnet electron cyclotron resonance plasma
Deposition of silicon nitride at low temperatures by plasma-enhanced chemical vapor deposition requires an efficient source of activated precursors and high-current, low-energy ion assist. We report the deposition of silicon nitride at substrate temperatures <100 degrees C using a permanent magnet electron cyclotron resonance plasma reactor capable of generating uniform plasmas over 300 mm diameters. The effects of gas mixture, silane flow, pressure, and microwave power on the film deposition rate, composition and bonding, index of refraction, stress, and etch rate in buffered oxide etch solution are reported. The N-2/SiH4 flow ratio and microwave power both influence the film index and hydrogen content and bonding. For a SiH4 flow of 30 seem and N-2/SiH4 similar to 0.75, hydrogen is equally distributed between Si-H and N-H sites and total hydrogen content is minimized. At a deposition rate of 500-600 Angstrom/min, a threshold in microwave power of similar to 1100 W exists, above which films with buffered oxide etch rates <150 Angstrom/min result. Near the threshold microwave power compressive stress <400 MPa is observed, with increasing stress at higher microwave powers.