화학공학소재연구정보센터
Journal of Vacuum Science & Technology B, Vol.15, No.6, 1902-1907, 1997
Expression for the growth rate of selective epitaxial growth of silicon using dichlorosilane, hydrogen chloride, and hydrogen in a low pressure chemical vapor deposition pancake reactor
A semiempirical expression was developed for the growth rate of selective epitaxial growth (SEG) and epitaxial lateral overgrowth of silicon in a rf heated cold-wall low pressure chemical vapor deposition pancake reactor for the dichlorosilane-HCl-H-2 system. The model was obtained for temperatures ranging from 920 to 1020 degrees C, system pressures from 40 to 150 Torr, and over a range of HCl and dichlorosilane gas flows. The growth rate expression is the sum of a growth term which is a function of the partial pressures of dichlorosilane (SiCl2H2) and hydrogen, and an etch term that varies with the partial pressure of HCl. The growth and etch terms have a temperature Arrhenius relation with activation energies of E-gr = 2.266 and E-et = 1.349 eV, respectively. Included is a term to account for the SEG growth rate dependence on the ratio of SiO2 area coverage to silicon wafer area. A methodology was developed for obtaining the coefficients for the semiempirical growth rate expression from several sets of experiments.