화학공학소재연구정보센터
Journal of Vacuum Science & Technology B, Vol.17, No.3, 930-932, 1999
Amorphous carbon films for use as both variable-transmission apertures and attenuated phase shift masks for deep ultraviolet lithography
We describe the development of amorphous carbon (a-C) films grown by magnetron sputtering for use in optical elements for sub-0.25-mu m deep ultraviolet (DUV) lithography. We have measured the transmittance of a-C films deposited onto quartz substrates as a function of him thickness, and find that the films are ideally suited for use in variable-transmission apertures that can be used to improve DUV process latitude: we can achieve essentially any transmittance (T) desired in the range 0t>0 nm with subnanometer precision. We also find that the transmittance remains stable after prolonged exposure to high intensity DUV radiation. We describe a masked deposition technique to produce variable-transmission apertures using a-C films of various thicknesses, and also discuss the use of these films in attenuated phase shift masks, given that we can simultaneously achieve similar to 6%-8% transmittance and a phase shift of 180 degrees at either lambda = 248 nm or 193 nm.