Langmuir, Vol.13, No.16, 4301-4304, 1997
Monte-Carlo Analysis of Hydrogen Interaction with Promoter-Modified and Inhibitor-Modified Nickel Surfaces
A Monte Carlo simulation analysis is performed of the kinetics of adsorption and desorption for the systems H + K/Ni(111) and H + O/Ni(111). Fundamental energetic parameters are determined by fitting simulation results to experimental data for thermal desorption spectra and sticking coefficients.
Keywords:TEMPERATURE-PROGRAMMED DESORPTION;ADSORBATE LATERAL INTERACTIONS;THERMAL-DESORPTION;REACTION-KINETICS;HETEROGENEOUS SURFACES;ADSORPTION;MOLECULES;SPECTRA;MODEL;SIMULATIONS