화학공학소재연구정보센터
Macromolecules, Vol.30, No.8, 2482-2494, 1997
Thin-Film Rheology and Tribology of Confined Polymer Melts - Contrasts with Bulk Properties
A modified Surface Forces Apparatus was used for making rheological and tribological measurements of thin fluid films, and polybutadiene (PBD) of M-w approximate to 7000 was studied in detail. At low shear rates, PBD exhibits bulklike properties in films thicker than about 200 nm. Ln thinner films (200-20 nm), the shear viscosity eta(eff) and moduli G’ and G " become quantitatively modified from those of the bulk. However, a sinusoidal input still produces a sinusoidal output, and a modified WLF representation remains applicable to such films. On entering the tribological regime (film thickness < 30 nm) polybutadiene exhibits highly nonlinear behavior and yield points, indicative of phase transitions to "glassy" or "solidlike" states. Other features are (i) a shift of the slip plane, (ii) an additional normal force component, and (iii) the emergence of new scaling relationships for eta(eff) GI, G ", and the friction force F as a function of frequency, sliding speed, and other system parameters.