Macromolecules, Vol.31, No.16, 5502-5506, 1998
Variational approach to necklace formation in polyelectrolytes
By means of a variational approach we study the conditions under which a polyelectrolyte in a bad solvent will undergo a transition from a rodlike structure to a "necklace" structure in which the chain collapses into a series of globules joined by stretched chain segments.
Keywords:PERSISTENCE LENGTH;POLYAMPHOLYTES