In this research, the role of zinc ferrite in the hydrometallurgical recovery of zinc in both primary zinc production and zinc-containing waste treatment processes is discussed. In the present work, experiments were performed on the caustic leaching of pure zinc ferrite. The effects of leaching time, caustic concentration and temperature were investigated in the deceleratory period. Atomic Absorption Spectroscopy (AAS) and X-Ray Diffraction (XRD) analyses were employed to analyze both the leach solutions and the residues. It was found that the percentage of decomposed zinc ferrite increased linearly with increasing leaching time. Although the decomposition rate increased with the caustic concentration, it was limited by the high viscosity of the concentrated leach solutions. The maximum percentage of decomposed zinc ferrite was only about 9% under the experimental conditions. Based on the experimental results, it was postulated that the dissolution rate of zinc ferrite in the deceleratory period, was controlled by the diffusion of zinc ions in the imperfect zinc ferrite lattice. The dissolution reaction could be represented as follows: ZnFe2O4 + 2[OH-] = ZnO22- + Fe2O3 + H2O.