Electronic Structural and Magnetic-Properties of (TTF)6(Net4)(Pmo12O40) - A Mixed-Valence TTF Salt with a Magnetic Polyoxometalate

Bellitto C; Staulo G; Bozio R; Pecile C

Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.234, 205-212, 1993

DOI10.1080/10587259308042917 Export Citation

Electronic Structural and Magnetic-Properties of (TTF)6(Net4)(Pmo12O40) - A Mixed-Valence TTF Salt with a Magnetic Polyoxometalate

Bellitto C, Staulo G, Bozio R, Pecile C

(TTF)6(NEt4)[PMo12O40] has been characterised by EPR, IR and Resonance Raman Spectroscopy and by static magnetic susceptibility. From all these data the compound can be formulated as : (Et4N)+(TTF-degrees)2(TTF)4(3+)[PMo12O40]4-. The magnetic and the electrical properties are accounted for on this basis.