Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.239, 95-105, 1994
Hard Ellipsoids in an Anisotropic Mean-Field - Surface Effects on the Isotropic-Nematic Phase-Transition
The surface effects on the isotropic-nematic phase transition are analyzed using a functional form of the surface energy which contains two terms : one linear term in the order parameter and the second proportional to the square of the order parameter. The first-order nematic-paranematic phase transition is found to take place only in limited ranges of substrate potential strengths. This transition is examined for p-azoxy-anisole (PAA) in the framework of "the hard ellipsoids in an anisotropic mean field" model.
Keywords:CRYSTAL-WALL INTERFACE;LIQUID-CRYSTAL;MOLECULAR THEORY;ANCHORING ENERGY;DIRECTOR ORIENTATION;SIMPLE-MODEL;STATISTICAL-MECHANICS;CRITICAL-BEHAVIOR;SPHEROCYLINDERS;SUBSTRATE