Poly mer-T CNQ(tetracy anoquinodimethane) charge transfer complexes were synthesized using organic polycations as electron donor. The materials were spin coated on the aluminium deposited poly carbonate substrate and their optical recording effects were tested at 830nm With the recording power of 8mW and recording speed of 1.2m/s, the maximum CNR(carrier to noise ratio) of 40dB was observed.