Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.292, 123-139, 1997
Amphotropic Properties of Multi-Palladium and Multi-Platinum Liquid-Crystals
Tetrametallomesogens containing palladium (2,3a-c) or platinum (4,5a-c) macroheterocyclic central cores show wide ranging liquid crystalline properties, both thermotropic and lyotropic in apolar organic solvents. Here, we present an overview of recent work from our laboratory concerning these novel metallomesogens and related bis-metal analogues 6 and 7. We also propose new nomenclature to satisfy the growing range of liquid crystalline mesophases exhibited by these materials.
Keywords:TRANSFER INDUCED MESOPHASES;ORDERED MESOPHASES;PHASE-BEHAVIOR;METAL;COMPLEXES;MESOGENS;ORGANYLS