화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.299, 419-426, 1997
Laterally Branched Mesogens Incorporating a Rigid Perfluoroalkyl Chain
We synthesized laterally aryl substituted mesogens derived from isophthalic acid (type A) and resorcylic acid (type B) containing a fluorinated alkyl-alkoxy chain in a terminal position. An increase of the clearing points and a stabilization of the smectic phases compared to the nonfluorinated references appear in all cases. Hereby, the position is not important for the height of the transition temperatures. There is a dependence on the number of methylene units between the oxygen and the fluoro-carbon groups in the type A derivatives.