화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.301, 343-349, 1997
Nematic Bend-Splay Elasticity of Cyanophenyl Compounds with Different Terminal Groups
The elastic properties of nematic compounds with terminal cyanoaromatic and containing cycles alyphatic groups were investigated. The terminal group structure has essential influence on the bend K-3 and splay K-1 elastic constants and their temperature dependences. The ninth and tenth members of 4-cyanophenyl 4’-n-alkyloxybenzoate series (nCPh) and cyanobiphenyl ether with ethylene-butylcyclohexane terminal group show pretransitional divergence of K-3 in the vicinity of the nematic-smectic phase transition Outside pretransitional temperature region the alternatation from odd to even n in nCPh series is accompanied by positive jumps of the ratio K-3/K-1 and change of the character of its temperature dependence. A striking unmonotonous temperature dependence of the elastic splay constant K-1 was founded for cyanobiphenyl ether with butylcyclohexane terminal group. The occurrence of frozen striped texture in a smectic phase after the nematic-smectic transition in the presence of magnetic field was found for all nematics with the temperature divergence of K-3. Distance between stripes was the less, the more magnetic induction.