Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.306, 501-506, 1997
Models for Charged Organic High-Spin Systems - Synthesis and Cyclic Voltammetry of One-Dimensional and 2-Dimensional Diarylaminobenzenes
A series of 1,3-di(diarylamino)benzenes (DABs) and 1,3,5-tris(diarylamino) benzenes (TABs) were synthesized as model precursors for polycationic pi-conjugated high-spin systems. CV measurement at low temperature showed that the chemical stability in solution of mono-and polycationic oxidation states of the various DABs and TABs derivatives depend on their structures. Correlation between the chemical stability of these cations and their molecular structure is discussed.