화학공학소재연구정보센터
Applied Catalysis B: Environmental, Vol.27, No.4, L213-L216, 2000
Remarkable enhancement in durability of Pd/H-ZSM-5 zeolite catalysts for CH4-SCR
Effect of second components on the catalytic performance of Pd/H-ZSM-5 zeolite (Pd: 0.4 wt.%) was evaluated by a durability test of NO reduction with CH4 at a relatively high temperature of 500 degrees C in the presence of water vapor for a prolonged period. The Pd/H-ZSM-5 showed high stable activity for this reaction without H2O in the reactant feed, while immediate and irreversible deactivation was observed in the presence of H2O, resulting in no activity after 7 h. The second components such as Co, Rh, Ag, Ce, and Fe introduced individually to the Pd/H-ZSM-5 enhanced the durability, and in particular the addition of 3.3 wt.% Co led to a stable NO conversion for more than 40 h in the presence of H2O.