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Applied Catalysis B: Environmental, Vol.18, No.3-4, 183-187, 1998
Carbon oxidation with platinum supported catalysts
The effect of the support oxide. Pt precursor and reactant gas composition on the catalysis of soot oxidation was investigated using carbon black as a model soot and simulated exhaust gases. The Pt precursors used were Pt(NH3)(4)(OH)(2), H(2)PtCl(6)6H(2)O, Pt(NH3)(4)(NO3)(2), and Pt(NH3)(4)Cl-2. The support metal oxides used were SiO2, Al2O3, and ZrO2. Pt/SiO2 prepared from Pt(NH3)(4)(OH)(2) showed the highest carbon oxidation activity. It had much higher activity in the condition of N-2+O-2+H2O+NO+SO2 than without NO and SO2.
Keywords:DIESEL EXHAUST-GASES, NITROGEN-OXIDES, SOOT, COMBUSTION;COPPER, PARTICULATE, ENGINES, REMOVAL