A rainbow measurement technique is presented which measures simultaneously the size, temperature and velocity of individual droplets in a spray. The technique is based on rainbow interferometry in combination with diffraction by a wire placed in the spatial filter of the scattered-light detector. A photomultiplier detects the wire diffraction pattern superimposed on the rainbow interference pattern created by a droplet scattering laser light. The velocity is determined from the equivalent geometric wire shadow. The necessary sphericity validation is performed by comparing the Airy and the ripple droplet diameters, resulting from the respective interference structures. The temperature is recovered from the position of the wire diffraction pattern relative to the main rainbow maximum. The technique was applied to a water spray at ambient temperature. The results showed the importance of non-sphericity detection.