화학공학소재연구정보센터
Polymer, Vol.36, No.3, 631-638, 1995
Electrosynthesis of Symmetrical Aramid Oligomers
Symmetrical aramid oligomers have been synthesized by dehalogenative polycondensation of two aryl dibromides containing primary amide structural units as monomers in the presence of electrogenerated zerovalent nickel acting as a catalyst. As the oligomers obtained were insoluble in organic solvents, they were characterized by solid-state n.m.r. spectroscopy, infra-red spectroscopy and elemental analysis. Analysis of the monomer and oligomer samples by X-ray diffraction shows that these symmetrical materials possess a better crystallinity than the related unsymmetrical compounds.