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Polymer, Vol.36, No.21, 4167-4171, 1995
TEM Study of Block-Copolymers Confined in Thin-Films
The behaviour of thin films of symmetric block copolymers of styrene and methyl methacrylate in contact with other polymers or with air is studied by transmission electron microscopy. The characteristic layer formation of the block copolymer in contact with vacuum or with a different, completely immiscible polymer can be observed. If one of the blocks is miscible with a contacting polymer, competitive mechanisms of swelling and diffusion are observed.