Polymer, Vol.39, No.14, 3083-3086, 1998
Gel-like behaviour of polybutadiene carbon black compounds
Recent experimental data of Cohen Addad and Frebourg on the adsorption of polybutadiene chains on the ISAF carbon black from bulk were compared with the polymer-filler gel formation theory. A very good agreement was obtained and the resulting parameter-values were similar to those recently determined for the SBR-ISAF black system. This lends support to the model upon which the theory is based : random adsorption of polymer segments, filler particles acting as a polyfunctional crosslinking agent. The Cohen Addad-Frebourg theoretical treatment of polybutadiene adsorption on carbon black (polymer chains bifunctional, dangling chains partially eliminated by the solvent) is critically reviewed.