화학공학소재연구정보센터
Polymer, Vol.39, No.19, 4535-4539, 1998
Molecular weight dependence of the lateral growth rate of polyethylene - 2. Folded-chain crystals
Molecular weight (M) dependence of the lateral growth rate (V) of folded chain crystals (FCCs) of polyethylenes (PE) was investigated. This study was carried out on single (or single crystal-like) crystals using the equilibrium melting temperature (T-m(0)) determined by applying Gibbs-Thomson's equation. The well-known relation V = V-0 exp( - B/Delta T) was obtained where V-0 and B are constants and Delta T is a degree of supercooling. V-0 strongly decreased with increase of M, whereas B did not, which indicates that the self-diffusion process of polymer chains mainly controls the M dependence of V, whereas the nucleation one does not. Experimental formula that V proportional to V-0 proportional to D proportional to M-H where D is self-diffusion constant and H is a constant; H = 1.7 was obtained. These results are similar to Hoffman et al.'s results but their H was rather smaller, H = 1-1.5. A similar study on extended-chain single crystals (ECSCs) reported in our previous paper gave the same experimental formula but H was much smaller, H = 0.7. From the difference in H between FCCs and ECSCs, a new proposal that M dependence of V may be mainly controlled by the surface diffusion process of chain polymers on the growing crystal surface, is discussed briefly.