Polymer, Vol.41, No.11, 4281-4284, 2000
Secondary transitions of aryl-aliphatic polyamides III. H-2 NMR investigation
H-2 NMR experiments were performed on a selectively deuterated aryl-aliphatic copolyamide in order to investigate the local dynamics of the phenyl rings as a function of temperature. The activation energy of the phenyl ring flip motion, determined from the H-2 NMR experiments, was shown to be identical to the activation energy determined by dielectric relaxation for the beta transition. Such a result tends to indicate that the phenyl ring flips are part of the beta transition in the aryl-aliphatic copolyamide under study. (C) 2000 Elsevier Science Ltd. All rights reserved.
Keywords:SPIN-LATTICE RELAXATION;SEGMENTAL DYNAMICS;POLY(P-PHENYLENETEREPHTHALAMIDE);MOTION;SOLIDS;ECHO