Four soluble styrenic polymers containing 3-substituted pendant pyrrole rings with ester or amide arm spacer were synthesized. Their electroactive characteristics were investigated by cyclic voltammetry. The chemical oxidation was accomplished by adding FeCl3 into a solution of styrenic polymers dissolved in 1:1 mixture of dimethylformamide (DMF) and acetonitrile (ACN). The electrical conductivities of the chemically oxidized black powder of the styrenic polymers were in the range of 10(-10)similar to 10(-9) S/cm.